Preparation and reactivity of metal-containing monomers View Full Text


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Article Info

DATE

1993-02

AUTHORS

E. I. Aleksandrova, G. I. Dzhardimalieva, A. S. Rosenberg, A. D. Pomogailo

ABSTRACT

The kinetics and mechanism of thermal decay of an unsaturated copper carboxylate, Cu(OCOCH=CH2)2 (CuAcr2), have been studied. At 190–240°C the rate of thermal decay can be adequately described by a set of zero and first order rate equations. The initial rate of decay,W0, is equal to 1.7·1017exp[-48500/(RT)] s−1. The decay products of CuAcr2 were analyzed by IR and mass spectroscopy as well as by optical microscopy. It has been established that the thermal decay of the monomer under study is accompanied by polymerization, fragmentation, and recombination processes in the solid phase which produce polymeric agglomerates. More... »

PAGES

259-263

References to SciGraph publications

  • 1990-11. Study of the thermal behaviour of several metal acrylates and methacrylates in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1983-03. The thermal decompositions of some transition metal acrylates and polyacrylates in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf00697072

    DOI

    http://dx.doi.org/10.1007/bf00697072

    DIMENSIONS

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