Preparation and reactivity of metal-containing monomers View Full Text


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Article Info

DATE

1993-10

AUTHORS

A. S. Rozenberg, E. I. Aleksandrova, G. I. Dzhardimalieva, A. N. Titkov, A. D. Pomogailo

ABSTRACT

The thermal decomposition of iron (III) acrylate, [Fe3O(CH2=CHCOO)6 · 3H2O]OH (FeAcr), a monomer with a complex cluster cation, has been studied at 200–370 °C. Thermal transformations of FeAcr occur in two temperature regions. The rates of gas evolution in the low temperature region (200–300 °C) and the high temperature region (300–370 °C) are described by first-order equations withk=4.2 · 1021exp[−59000/(RT)] s−1 andk=1.3 · 106exp[−30500/(RT)] s−1, respectively. A study of the qualitative and quantitative composition of the products of FeAcr thermolysis was carried out. The thermal transformation of FeAcr is a complex process of dehydration, degradation, and polymerization in the solid phase followed by decarboxylation of the metal-carboxyl groups of the polymer. More... »

PAGES

1666-1672

References to SciGraph publications

  • 1993-02. Preparation and reactivity of metal-containing monomers in RUSSIAN CHEMICAL BULLETIN
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf00697036

    DOI

    http://dx.doi.org/10.1007/bf00697036

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1038060381


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