Preparation and reactivity of metal-containing monomers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-10

AUTHORS

Yu. M. Shul'ga, O. S. Roshchupkina, G. I. Dzhardimalieva, I. V. Chernushevich, A. F. Dodonov, Yu. V. Baldokhin, P. Ya. Kolotyrkin, A. S. Rozenberg, A. D. Pomogailo

ABSTRACT

A new cluster-type monomer [Fe3O(OCOCH=CH2)6]OH · 3H2O was synthesized by the reaction of acrylic acid with freshly prepared iron hydroxide. The monomer was characterized by various physicochemical methods. It has been shown that the acid residues are bound to the metal atoms through carboxyl groups in a bridge-like or bidentate fashion, and the double bond does not participate in the coordination. The mechanism of thermal fragmentation of the [Fe3O(OCOCH=CH2)6]+ cluster was studied. It was demonstrated that the radical polymerization of this monomer involved bidentate acrylate groups. No reduction of Fe3+ during the polymerization was observed. More... »

PAGES

1661-1665

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00697035

DOI

http://dx.doi.org/10.1007/bf00697035

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043299613


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