Thermal decomposition of 1-ethyl-5-iodotetrazole View Full Text


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Article Info

DATE

1994-11

AUTHORS

V. V. Nedel'ko, B. L. Korsounskii, T. S. Larikova, V. R. Stepanov, N. V. Chukanov, I. V. Nedel'ko

ABSTRACT

The thermal decomposition of 1-ethyl-5-iodotetrazole in a melt and in solutions was studied using thermogravimetry, manometry, pyrolytic mass spectrometry, and IR spectroscopy. The kinetic and activation parameters of the process and the nature of the decomposition products were determined. The reaction mechanism is assumed to involve equilibrium tautomeric rearrangement of the tetrazole to azidoazomethine form followed by homolytic cleavage of the C-I bond. More... »

PAGES

1812-1815

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00696307

DOI

http://dx.doi.org/10.1007/bf00696307

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052092642


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