A new direct formation of benzyllithium reagent on an insoluble polymer View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-06

AUTHORS

Shinichi Itsuno, Koji Shimizu, Koichi Kamahori, Koichi Ito

ABSTRACT

Hydrogen-metal exchange reactions using butyllithium have been studied on cross-linked poly(4-methylstyrene) to prepare polymer-bound benzyllithium reagent, which is a valuable starting material for functionalized resins. A simple one-step lithiation of pendant tolyl group of poly(4-methylstyrene) was achieved with a degree of lithiation as high as 50% using t-butyllithium in tetrahydrofuran.

PAGES

177-181

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00683795

DOI

http://dx.doi.org/10.1007/bf00683795

DIMENSIONS

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