Synthesis and characterization of soluble (porphyrinato)iron(II) polymers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1994-09

AUTHORS

Jürgen Pawlik, Christian Kautz, Martin Baumgarten

ABSTRACT

The use of (tetrakis(4-hexylphenyl)porphyrinato)Fe(II) in polymerization reactions with bidentate ligands such as 9,10-diisocyanoanthracene and 1,4-diisocyanobenzene led to well-defined stacked polymers1 and2 which are still soluble in common organic solvents such as chloroform, dichloromethane, and tetrahydrofurane. They have been completely characterized by1H-NMR and UV/vis spectropscopy in solution, even allowing end-group analysis for determination of the average degree of polymerization, yieldingn=10 andn=5 for1 and2, respectively. Mößbauer and IR spectroscopy further established the strong Fe-CN bonding reflected by very small isomer shifts and quadrupole splittings (ΔEQ∼0.2 mm s−1) and a large decrease in the IR stretching frequency (ΔvCN∼60 cm−1). The axially stacked polymers exhibit semiconducting properties only upon doping. More... »

PAGES

237-250

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00683717

DOI

http://dx.doi.org/10.1007/bf00683717

DIMENSIONS

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