High-temperature oxidation of zirconium-hydride powders View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1992-08

AUTHORS

V. Zh. Shemet, V. A. Lavrenko, O. A. Teplov, V. Zh. Ratushnaya

ABSTRACT

The oxidation kinetics of zirconium-hydride powders were studied in the temperature range of 298–1378 in air at atmospheric pressure. TG, DTA, DSC, x-ray analysis, and scanning electron microscopy were used. The results obtained are in accordance with the proposed pseudo-parabolic model of zirconium-hydride oxidation. This model includes the initial linear mode of oxide growth with oxygen diffusion through a non-solid film of ZrO2 of variable depth and a stationary diffusion process followed by oxide sintering. It has been established that the activation energy of the limiting stage of oxidation (238.3 kJ/mol) coincides with the activation energy of oxygen self-diffusion in monocline ZrO2. More... »

PAGES

89-98

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00665046

DOI

http://dx.doi.org/10.1007/bf00665046

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002623390


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