Comments on a model for isotope effects on Henry's law constants in aqueous solution View Full Text


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Article Info

DATE

1981-05

AUTHORS

Philippe Bopp, Max Wolfsberg

ABSTRACT

A model has been proposed in the literature for isotope effects on Henry's law constants in which the motion of the dissolved molecule surrounded by a solvent cage is approximated by the motion of a particle in a cubic box. The isotope effect then arises from the three free translations of the gas phase molecule which become the restricted translations of a particle in a box for the dissolved molecule. The theoretical equation for the isotope effect is derived here on the basis of this model. Zero-point energy arguments have been used in the literature in conjunction with this model to deduce solvent cage dimensions from observed isotope effect data. These arguments are shown here to be theoretically wrong. The correct theory for the particle in a box model gives much larger dimensions for the solvent cage than the incorrect zero-point energy argument. More... »

PAGES

357-361

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00647041

DOI

http://dx.doi.org/10.1007/bf00647041

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006484022


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