Excess volumes of aqueous mixtures of the zwitterion and the acid chloride salt of L-amino acids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1984-04

AUTHORS

J. Vliegen, J. Yperman, J. Mullens, J. P. François, L. C. Van Poucke

ABSTRACT

The apparent molar volumes of the zwitterion (HL) and the chloride salt form (H2LCl) and their mixtures (HL/H2LCl) of glycine, L-serine and L-proline have been measured in aqueous solutions at 25°C. From these experimental data the excess apparent molar volumes of the HL/H2LCl mixtures have been calculated. An attempt is made to explain these excess volume properties in terms of intermolecular hydrogen bond formation between the solute molecules HL and H2LCl when forming the dimer H3L2Cl. More... »

PAGES

245-257

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00646398

DOI

http://dx.doi.org/10.1007/bf00646398

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027037821


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