Chlorination of N-tritylproline methyl ester View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1988-07

AUTHORS

F. D. Polyak, A. V. Eremeev, M. P. Gavars, A. P. Gaukhman, I. B. Mazheika

ABSTRACT

The reaction of N-tritylproline methyl ester with tert-butyl hypochlorite gave 2,4-dichloro-2-methoxycarbonyl-5-pyrroline, which is readily converted to 2-methoxycarbonyl-4-chloropyrrole. The intermediate products were identified by Chromatographic mass spectrometry when the reaction was carried out at low temperatures.

PAGES

733-735

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00633164

DOI

http://dx.doi.org/10.1007/bf00633164

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000203715


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga", 
          "id": "http://www.grid.ac/institutes/grid.419212.d", 
          "name": [
            "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Polyak", 
        "givenName": "F. D.", 
        "id": "sg:person.07771367336.99", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07771367336.99"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga", 
          "id": "http://www.grid.ac/institutes/grid.419212.d", 
          "name": [
            "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Eremeev", 
        "givenName": "A. V.", 
        "id": "sg:person.014471236413.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014471236413.16"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga", 
          "id": "http://www.grid.ac/institutes/grid.419212.d", 
          "name": [
            "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gavars", 
        "givenName": "M. P.", 
        "id": "sg:person.011205565373.86", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011205565373.86"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga", 
          "id": "http://www.grid.ac/institutes/grid.419212.d", 
          "name": [
            "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gaukhman", 
        "givenName": "A. P.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga", 
          "id": "http://www.grid.ac/institutes/grid.419212.d", 
          "name": [
            "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mazheika", 
        "givenName": "I. B.", 
        "id": "sg:person.015222644673.69", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015222644673.69"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1988-07", 
    "datePublishedReg": "1988-07-01", 
    "description": "The reaction of N-tritylproline methyl ester with tert-butyl hypochlorite gave 2,4-dichloro-2-methoxycarbonyl-5-pyrroline, which is readily converted to 2-methoxycarbonyl-4-chloropyrrole. The intermediate products were identified by Chromatographic mass spectrometry when the reaction was carried out at low temperatures.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf00633164", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1429545", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "24"
      }
    ], 
    "keywords": [
      "tert-butyl hypochlorite", 
      "chromatographic mass spectrometry", 
      "methyl ester", 
      "mass spectrometry", 
      "intermediate products", 
      "reaction", 
      "low temperature", 
      "esters", 
      "spectrometry", 
      "pyrroline", 
      "chlorination", 
      "hypochlorite", 
      "products", 
      "temperature"
    ], 
    "name": "Chlorination of N-tritylproline methyl ester", 
    "pagination": "733-735", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1000203715"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00633164"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00633164", 
      "https://app.dimensions.ai/details/publication/pub.1000203715"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-11-24T20:46", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221124/entities/gbq_results/article/article_182.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf00633164"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00633164'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00633164'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00633164'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00633164'


 

This table displays all metadata directly associated to this object as RDF triples.

98 TRIPLES      20 PREDICATES      39 URIs      31 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00633164 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Na6e4b108c1d8479b8a9da6099dd75620
4 schema:datePublished 1988-07
5 schema:datePublishedReg 1988-07-01
6 schema:description The reaction of N-tritylproline methyl ester with tert-butyl hypochlorite gave 2,4-dichloro-2-methoxycarbonyl-5-pyrroline, which is readily converted to 2-methoxycarbonyl-4-chloropyrrole. The intermediate products were identified by Chromatographic mass spectrometry when the reaction was carried out at low temperatures.
7 schema:genre article
8 schema:isAccessibleForFree false
9 schema:isPartOf Necc229f449b84b61a9463e147df7c20d
10 Nfc84838d2d2e4d74930a8d311409c8d5
11 sg:journal.1429545
12 schema:keywords chlorination
13 chromatographic mass spectrometry
14 esters
15 hypochlorite
16 intermediate products
17 low temperature
18 mass spectrometry
19 methyl ester
20 products
21 pyrroline
22 reaction
23 spectrometry
24 temperature
25 tert-butyl hypochlorite
26 schema:name Chlorination of N-tritylproline methyl ester
27 schema:pagination 733-735
28 schema:productId N5e32e0fe16ba4312bdab89e65f0b4cb4
29 Ne0a553c899444cef97071cbf97680e75
30 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000203715
31 https://doi.org/10.1007/bf00633164
32 schema:sdDatePublished 2022-11-24T20:46
33 schema:sdLicense https://scigraph.springernature.com/explorer/license/
34 schema:sdPublisher Naf168e0dcdab405ba1e65b7eefb84021
35 schema:url https://doi.org/10.1007/bf00633164
36 sgo:license sg:explorer/license/
37 sgo:sdDataset articles
38 rdf:type schema:ScholarlyArticle
39 N3d51a7f91c414b32bf4bd99e2b7b16b6 rdf:first sg:person.011205565373.86
40 rdf:rest Nb426541e69044531a44d18ce51347e9b
41 N4cfb926d2c4f416b8913e6524fd114e1 schema:affiliation grid-institutes:grid.419212.d
42 schema:familyName Gaukhman
43 schema:givenName A. P.
44 rdf:type schema:Person
45 N52c2915ede44475bb2f64138cc028704 rdf:first sg:person.014471236413.16
46 rdf:rest N3d51a7f91c414b32bf4bd99e2b7b16b6
47 N5e32e0fe16ba4312bdab89e65f0b4cb4 schema:name dimensions_id
48 schema:value pub.1000203715
49 rdf:type schema:PropertyValue
50 N86f31a8fcfa742e19a33aa8c807e22cb rdf:first sg:person.015222644673.69
51 rdf:rest rdf:nil
52 Na6e4b108c1d8479b8a9da6099dd75620 rdf:first sg:person.07771367336.99
53 rdf:rest N52c2915ede44475bb2f64138cc028704
54 Naf168e0dcdab405ba1e65b7eefb84021 schema:name Springer Nature - SN SciGraph project
55 rdf:type schema:Organization
56 Nb426541e69044531a44d18ce51347e9b rdf:first N4cfb926d2c4f416b8913e6524fd114e1
57 rdf:rest N86f31a8fcfa742e19a33aa8c807e22cb
58 Ne0a553c899444cef97071cbf97680e75 schema:name doi
59 schema:value 10.1007/bf00633164
60 rdf:type schema:PropertyValue
61 Necc229f449b84b61a9463e147df7c20d schema:volumeNumber 24
62 rdf:type schema:PublicationVolume
63 Nfc84838d2d2e4d74930a8d311409c8d5 schema:issueNumber 7
64 rdf:type schema:PublicationIssue
65 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
66 schema:name Chemical Sciences
67 rdf:type schema:DefinedTerm
68 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
69 schema:name Physical Chemistry (incl. Structural)
70 rdf:type schema:DefinedTerm
71 sg:journal.1429545 schema:issn 0132-6244
72 1573-8353
73 schema:name Chemistry of Heterocyclic Compounds
74 schema:publisher Springer Nature
75 rdf:type schema:Periodical
76 sg:person.011205565373.86 schema:affiliation grid-institutes:grid.419212.d
77 schema:familyName Gavars
78 schema:givenName M. P.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011205565373.86
80 rdf:type schema:Person
81 sg:person.014471236413.16 schema:affiliation grid-institutes:grid.419212.d
82 schema:familyName Eremeev
83 schema:givenName A. V.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014471236413.16
85 rdf:type schema:Person
86 sg:person.015222644673.69 schema:affiliation grid-institutes:grid.419212.d
87 schema:familyName Mazheika
88 schema:givenName I. B.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015222644673.69
90 rdf:type schema:Person
91 sg:person.07771367336.99 schema:affiliation grid-institutes:grid.419212.d
92 schema:familyName Polyak
93 schema:givenName F. D.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07771367336.99
95 rdf:type schema:Person
96 grid-institutes:grid.419212.d schema:alternateName Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga
97 schema:name Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga
98 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...