Mass spectra of pseudoguaianolides related to carpesiolin View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-07-01

AUTHORS

V. N. Plugar', Ya. V. Rashkes, A. Ovezdurdyev, I. D. Sham'yanov

ABSTRACT

The main directions of fragmentation and the EI of six pseudoguaianolides related to carpesiolin have been studied. It has been established that acylation of the OH group at C-6 suppresses the selective breakdown of the guaiane skeleton, while the simultaneous presence of AcO groups at C-2 and C-4 favors the formation of a number of characteristic ions. The hydrogenation of the exomethylene group has no appreciable influence on direction of fragmentation. More... »

PAGES

462-466

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00630571

DOI

http://dx.doi.org/10.1007/bf00630571

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036510318


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "familyName": "Plugar'", 
        "givenName": "V. N.", 
        "id": "sg:person.014472237311.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014472237311.64"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Rashkes", 
        "givenName": "Ya. V.", 
        "id": "sg:person.012212616173.44", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012212616173.44"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Ovezdurdyev", 
        "givenName": "A.", 
        "id": "sg:person.010064052474.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010064052474.52"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Sham'yanov", 
        "givenName": "I. D.", 
        "id": "sg:person.012374162176.65", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012374162176.65"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1993-07-01", 
    "datePublishedReg": "1993-07-01", 
    "description": "The main directions of fragmentation and the EI of six pseudoguaianolides related to carpesiolin have been studied. It has been established that acylation of the OH group at C-6 suppresses the selective breakdown of the guaiane skeleton, while the simultaneous presence of AcO groups at C-2 and C-4 favors the formation of a number of characteristic ions. The hydrogenation of the exomethylene group has no appreciable influence on direction of fragmentation.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf00630571", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1009660", 
        "issn": [
          "0009-3130", 
          "1573-8388"
        ], 
        "name": "Chemistry of Natural Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "29"
      }
    ], 
    "keywords": [
      "ACO group", 
      "group", 
      "simultaneous presence", 
      "selective breakdown", 
      "fragmentation", 
      "presence", 
      "number", 
      "appreciable influence", 
      "EI", 
      "pseudoguaianolides", 
      "breakdown", 
      "guaiane skeleton", 
      "skeleton", 
      "C-6", 
      "C-2", 
      "C-4", 
      "formation", 
      "influence", 
      "direction", 
      "acylation", 
      "characteristic ions", 
      "exomethylene group", 
      "spectra", 
      "main directions", 
      "OH groups", 
      "ions", 
      "mass spectra", 
      "direction of fragmentation", 
      "hydrogenation", 
      "carpesiolin"
    ], 
    "name": "Mass spectra of pseudoguaianolides related to carpesiolin", 
    "pagination": "462-466", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1036510318"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00630571"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00630571", 
      "https://app.dimensions.ai/details/publication/pub.1036510318"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:00", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_255.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf00630571"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00630571'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00630571'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00630571'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00630571'


 

This table displays all metadata directly associated to this object as RDF triples.

110 TRIPLES      21 PREDICATES      57 URIs      47 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00630571 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 anzsrc-for:09
4 anzsrc-for:0904
5 schema:author N885fbc9fa2ea4c7a8a84d0b65304ff71
6 schema:datePublished 1993-07-01
7 schema:datePublishedReg 1993-07-01
8 schema:description The main directions of fragmentation and the EI of six pseudoguaianolides related to carpesiolin have been studied. It has been established that acylation of the OH group at C-6 suppresses the selective breakdown of the guaiane skeleton, while the simultaneous presence of AcO groups at C-2 and C-4 favors the formation of a number of characteristic ions. The hydrogenation of the exomethylene group has no appreciable influence on direction of fragmentation.
9 schema:genre article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N15005e026cae472cbf62477a84c60df4
13 N259b55ceeb394af8b63a61becf865f10
14 sg:journal.1009660
15 schema:keywords ACO group
16 C-2
17 C-4
18 C-6
19 EI
20 OH groups
21 acylation
22 appreciable influence
23 breakdown
24 carpesiolin
25 characteristic ions
26 direction
27 direction of fragmentation
28 exomethylene group
29 formation
30 fragmentation
31 group
32 guaiane skeleton
33 hydrogenation
34 influence
35 ions
36 main directions
37 mass spectra
38 number
39 presence
40 pseudoguaianolides
41 selective breakdown
42 simultaneous presence
43 skeleton
44 spectra
45 schema:name Mass spectra of pseudoguaianolides related to carpesiolin
46 schema:pagination 462-466
47 schema:productId Nd1ea7e0346f644b0b9335484e489b2ec
48 Nf28d9d923db54a5fa79bcd8a72fd227d
49 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036510318
50 https://doi.org/10.1007/bf00630571
51 schema:sdDatePublished 2021-11-01T18:00
52 schema:sdLicense https://scigraph.springernature.com/explorer/license/
53 schema:sdPublisher N437199c0105e491985856a4bba88046f
54 schema:url https://doi.org/10.1007/bf00630571
55 sgo:license sg:explorer/license/
56 sgo:sdDataset articles
57 rdf:type schema:ScholarlyArticle
58 N15005e026cae472cbf62477a84c60df4 schema:volumeNumber 29
59 rdf:type schema:PublicationVolume
60 N259b55ceeb394af8b63a61becf865f10 schema:issueNumber 4
61 rdf:type schema:PublicationIssue
62 N437199c0105e491985856a4bba88046f schema:name Springer Nature - SN SciGraph project
63 rdf:type schema:Organization
64 N478d2d0ed8f84069b57944f33ab38143 rdf:first sg:person.012374162176.65
65 rdf:rest rdf:nil
66 N885fbc9fa2ea4c7a8a84d0b65304ff71 rdf:first sg:person.014472237311.64
67 rdf:rest Ne893a28722a14426bca70ef18fd84f95
68 N8a3380cd7cbc407c95a02a36689539e9 rdf:first sg:person.010064052474.52
69 rdf:rest N478d2d0ed8f84069b57944f33ab38143
70 Nd1ea7e0346f644b0b9335484e489b2ec schema:name dimensions_id
71 schema:value pub.1036510318
72 rdf:type schema:PropertyValue
73 Ne893a28722a14426bca70ef18fd84f95 rdf:first sg:person.012212616173.44
74 rdf:rest N8a3380cd7cbc407c95a02a36689539e9
75 Nf28d9d923db54a5fa79bcd8a72fd227d schema:name doi
76 schema:value 10.1007/bf00630571
77 rdf:type schema:PropertyValue
78 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
79 schema:name Chemical Sciences
80 rdf:type schema:DefinedTerm
81 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
82 schema:name Organic Chemistry
83 rdf:type schema:DefinedTerm
84 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
85 schema:name Engineering
86 rdf:type schema:DefinedTerm
87 anzsrc-for:0904 schema:inDefinedTermSet anzsrc-for:
88 schema:name Chemical Engineering
89 rdf:type schema:DefinedTerm
90 sg:journal.1009660 schema:issn 0009-3130
91 1573-8388
92 schema:name Chemistry of Natural Compounds
93 schema:publisher Springer Nature
94 rdf:type schema:Periodical
95 sg:person.010064052474.52 schema:familyName Ovezdurdyev
96 schema:givenName A.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010064052474.52
98 rdf:type schema:Person
99 sg:person.012212616173.44 schema:familyName Rashkes
100 schema:givenName Ya. V.
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012212616173.44
102 rdf:type schema:Person
103 sg:person.012374162176.65 schema:familyName Sham'yanov
104 schema:givenName I. D.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012374162176.65
106 rdf:type schema:Person
107 sg:person.014472237311.64 schema:familyName Plugar'
108 schema:givenName V. N.
109 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014472237311.64
110 rdf:type schema:Person
 




Preview window. Press ESC to close (or click here)


...