The chemical interaction of metals with polytetrafluoroethylene View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1979-11

AUTHORS

P. Cadman, G. M. Gossedge

ABSTRACT

Chemical reactions of cadmium, indium and tin with PTFE have been found to occur when mixtures of the metal and polymer were heated in a differential scanning calorimeter to 773 K. Analysis of the residues by X-ray photoelectron spectroscopy (XPS) showed the presence of fluoride ions. The evaporation of a metal film on to the clean polymer surface has also been found by XPS to produce metal fluoride for nickel, cadmium, tin, indium and lead but not silver or gold. The rubbing of aluminium on to PTFE also produces reaction to give fluoride. The PTFE polymer molecules have been found to diffuse to the surface of metal/polymer composites at a significant rate. This latter process may be important in the use of this polymer in bearing materials. More... »

PAGES

2672-2678

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00610638

DOI

http://dx.doi.org/10.1007/bf00610638

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051488599


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Aberystwyth University", 
          "id": "https://www.grid.ac/institutes/grid.8186.7", 
          "name": [
            "Edward Davies Chemical Laboratories, University College of Wales, Aberystwyth, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Cadman", 
        "givenName": "P.", 
        "id": "sg:person.013262717675.21", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013262717675.21"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Aberystwyth University", 
          "id": "https://www.grid.ac/institutes/grid.8186.7", 
          "name": [
            "Edward Davies Chemical Laboratories, University College of Wales, Aberystwyth, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gossedge", 
        "givenName": "G. M.", 
        "id": "sg:person.015335642711.46", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015335642711.46"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1098/rspa.1972.0112", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006811166"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0043-1648(76)90187-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009954899"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0043-1648(76)90187-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009954899"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0043-1648(73)90151-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018435276"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0043-1648(73)90151-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018435276"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.1962.070062017", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023854220"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0008-6223(75)90052-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029726200"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0008-6223(75)90052-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029726200"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/polc.5070340125", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029960051"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/polc.5070340125", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029960051"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0043-1648(79)90115-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032264962"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0043-1648(79)90115-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032264962"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00549323", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040611728", 
          "https://doi.org/10.1007/bf00549323"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00549323", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040611728", 
          "https://doi.org/10.1007/bf00549323"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0043-1648(73)90081-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043974159"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0043-1648(73)90081-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043974159"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0043-1648(78)90054-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053044909"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0043-1648(78)90054-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053044909"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0013-4686(75)85036-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053496693"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0370-1301/65/9/302", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1059092282"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://app.dimensions.ai/details/publication/pub.1076899814", 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1979-11", 
    "datePublishedReg": "1979-11-01", 
    "description": "Chemical reactions of cadmium, indium and tin with PTFE have been found to occur when mixtures of the metal and polymer were heated in a differential scanning calorimeter to 773 K. Analysis of the residues by X-ray photoelectron spectroscopy (XPS) showed the presence of fluoride ions. The evaporation of a metal film on to the clean polymer surface has also been found by XPS to produce metal fluoride for nickel, cadmium, tin, indium and lead but not silver or gold. The rubbing of aluminium on to PTFE also produces reaction to give fluoride. The PTFE polymer molecules have been found to diffuse to the surface of metal/polymer composites at a significant rate. This latter process may be important in the use of this polymer in bearing materials.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00610638", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1312116", 
        "issn": [
          "0022-2461", 
          "1573-4811"
        ], 
        "name": "Journal of Materials Science", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "11", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "14"
      }
    ], 
    "name": "The chemical interaction of metals with polytetrafluoroethylene", 
    "pagination": "2672-2678", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "f5450e4c8ab573371beff7cf14143dbd590d161b56bf640ba010f194e93573ca"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00610638"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1051488599"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00610638", 
      "https://app.dimensions.ai/details/publication/pub.1051488599"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:50", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000371_0000000371/records_130797_00000004.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/BF00610638"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00610638'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00610638'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00610638'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00610638'


 

This table displays all metadata directly associated to this object as RDF triples.

107 TRIPLES      21 PREDICATES      40 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00610638 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N61862e8a0b72461f94132e23982b5df2
4 schema:citation sg:pub.10.1007/bf00549323
5 https://app.dimensions.ai/details/publication/pub.1076899814
6 https://doi.org/10.1002/app.1962.070062017
7 https://doi.org/10.1002/polc.5070340125
8 https://doi.org/10.1016/0008-6223(75)90052-4
9 https://doi.org/10.1016/0013-4686(75)85036-5
10 https://doi.org/10.1016/0043-1648(73)90081-1
11 https://doi.org/10.1016/0043-1648(73)90151-8
12 https://doi.org/10.1016/0043-1648(76)90187-3
13 https://doi.org/10.1016/0043-1648(78)90054-6
14 https://doi.org/10.1016/0043-1648(79)90115-7
15 https://doi.org/10.1088/0370-1301/65/9/302
16 https://doi.org/10.1098/rspa.1972.0112
17 schema:datePublished 1979-11
18 schema:datePublishedReg 1979-11-01
19 schema:description Chemical reactions of cadmium, indium and tin with PTFE have been found to occur when mixtures of the metal and polymer were heated in a differential scanning calorimeter to 773 K. Analysis of the residues by X-ray photoelectron spectroscopy (XPS) showed the presence of fluoride ions. The evaporation of a metal film on to the clean polymer surface has also been found by XPS to produce metal fluoride for nickel, cadmium, tin, indium and lead but not silver or gold. The rubbing of aluminium on to PTFE also produces reaction to give fluoride. The PTFE polymer molecules have been found to diffuse to the surface of metal/polymer composites at a significant rate. This latter process may be important in the use of this polymer in bearing materials.
20 schema:genre research_article
21 schema:inLanguage en
22 schema:isAccessibleForFree false
23 schema:isPartOf N4468e5845baa4290a67445135c24906e
24 N82e6d000f3b448e689f024de5e7f61cb
25 sg:journal.1312116
26 schema:name The chemical interaction of metals with polytetrafluoroethylene
27 schema:pagination 2672-2678
28 schema:productId N49f7b09038c74d71adb96f760f147d76
29 Nb16988b1b7514532b5cd8ba9d1cc27b2
30 Nda0b87b7fbe14ad4b1f6d555f95376df
31 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051488599
32 https://doi.org/10.1007/bf00610638
33 schema:sdDatePublished 2019-04-11T13:50
34 schema:sdLicense https://scigraph.springernature.com/explorer/license/
35 schema:sdPublisher N3e2f5c6755854a4f819c97351efa4ac7
36 schema:url http://link.springer.com/10.1007/BF00610638
37 sgo:license sg:explorer/license/
38 sgo:sdDataset articles
39 rdf:type schema:ScholarlyArticle
40 N3e2f5c6755854a4f819c97351efa4ac7 schema:name Springer Nature - SN SciGraph project
41 rdf:type schema:Organization
42 N4468e5845baa4290a67445135c24906e schema:issueNumber 11
43 rdf:type schema:PublicationIssue
44 N49f7b09038c74d71adb96f760f147d76 schema:name doi
45 schema:value 10.1007/bf00610638
46 rdf:type schema:PropertyValue
47 N61862e8a0b72461f94132e23982b5df2 rdf:first sg:person.013262717675.21
48 rdf:rest Nfe21adb797e848ce96a8603c6d0dcc33
49 N82e6d000f3b448e689f024de5e7f61cb schema:volumeNumber 14
50 rdf:type schema:PublicationVolume
51 Nb16988b1b7514532b5cd8ba9d1cc27b2 schema:name readcube_id
52 schema:value f5450e4c8ab573371beff7cf14143dbd590d161b56bf640ba010f194e93573ca
53 rdf:type schema:PropertyValue
54 Nda0b87b7fbe14ad4b1f6d555f95376df schema:name dimensions_id
55 schema:value pub.1051488599
56 rdf:type schema:PropertyValue
57 Nfe21adb797e848ce96a8603c6d0dcc33 rdf:first sg:person.015335642711.46
58 rdf:rest rdf:nil
59 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
60 schema:name Chemical Sciences
61 rdf:type schema:DefinedTerm
62 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
63 schema:name Physical Chemistry (incl. Structural)
64 rdf:type schema:DefinedTerm
65 sg:journal.1312116 schema:issn 0022-2461
66 1573-4811
67 schema:name Journal of Materials Science
68 rdf:type schema:Periodical
69 sg:person.013262717675.21 schema:affiliation https://www.grid.ac/institutes/grid.8186.7
70 schema:familyName Cadman
71 schema:givenName P.
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013262717675.21
73 rdf:type schema:Person
74 sg:person.015335642711.46 schema:affiliation https://www.grid.ac/institutes/grid.8186.7
75 schema:familyName Gossedge
76 schema:givenName G. M.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015335642711.46
78 rdf:type schema:Person
79 sg:pub.10.1007/bf00549323 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040611728
80 https://doi.org/10.1007/bf00549323
81 rdf:type schema:CreativeWork
82 https://app.dimensions.ai/details/publication/pub.1076899814 schema:CreativeWork
83 https://doi.org/10.1002/app.1962.070062017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023854220
84 rdf:type schema:CreativeWork
85 https://doi.org/10.1002/polc.5070340125 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029960051
86 rdf:type schema:CreativeWork
87 https://doi.org/10.1016/0008-6223(75)90052-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029726200
88 rdf:type schema:CreativeWork
89 https://doi.org/10.1016/0013-4686(75)85036-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053496693
90 rdf:type schema:CreativeWork
91 https://doi.org/10.1016/0043-1648(73)90081-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043974159
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1016/0043-1648(73)90151-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018435276
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1016/0043-1648(76)90187-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009954899
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1016/0043-1648(78)90054-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053044909
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1016/0043-1648(79)90115-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032264962
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1088/0370-1301/65/9/302 schema:sameAs https://app.dimensions.ai/details/publication/pub.1059092282
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1098/rspa.1972.0112 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006811166
104 rdf:type schema:CreativeWork
105 https://www.grid.ac/institutes/grid.8186.7 schema:alternateName Aberystwyth University
106 schema:name Edward Davies Chemical Laboratories, University College of Wales, Aberystwyth, UK
107 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...