The semiconductivity and stability of palladium oxide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1978-04

AUTHORS

E. Rey, M. R. Kamal, R. B. Miles, B. S. H. Royce

ABSTRACT

Films of palladium oxide of good optical quality have been prepared by the oxidation of sputtered films of palladium. Optical absorption and photoconductivity measurements indicate extrapolated band gaps of 2.13±0.03 eV and 2.67±0.03 eV respectively with the photoconductivity showing an exponential tail extending to lower energies. Measurements of the thermal stability of the films in the presence of a low partial pressure of oxygen indicate a dissociation enthalpy of −1.17±0.06 eV. The presence of hydrogen in the ambient during decomposition was found to reduce the temperature for decomposition to palladium metal from about 580 to 350 K. More... »

PAGES

812-816

Journal

TITLE

Journal of Materials Science

ISSUE

4

VOLUME

13

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00570517

DOI

http://dx.doi.org/10.1007/bf00570517

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034644802


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