Circular dichroism of some chlorine-containing guaianolides View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1979-09

AUTHORS

G. P. Moiseeva, I. D. Sham'yanov, A. Mallabaev, M. R. Yagudaev, G. P. Sidyakin

ABSTRACT

A study of the circular dichroism of chlorine-containing guainolides has shown that a negative Cotton effect in the 260-nm region correlates with the trans-linkage of the lactone ring in acroptilin, hyrcanin, chlorohyssopifolin B, elegin, and biebsanin. It has been established that this nature of the linkage does not change on relactonization and hydrogenation. A chloromethylene substituent at C4 causes a bathochromic shift of the lactone Cotton effect. More... »

PAGES

569-571

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00565926

DOI

http://dx.doi.org/10.1007/bf00565926

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050907620


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "familyName": "Moiseeva", 
        "givenName": "G. P.", 
        "id": "sg:person.013736062563.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013736062563.28"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Sham'yanov", 
        "givenName": "I. D.", 
        "id": "sg:person.012374162176.65", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012374162176.65"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Mallabaev", 
        "givenName": "A.", 
        "id": "sg:person.010225514060.51", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010225514060.51"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Yagudaev", 
        "givenName": "M. R.", 
        "id": "sg:person.010760410113.88", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010760410113.88"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Sidyakin", 
        "givenName": "G. P.", 
        "id": "sg:person.010334327723.74", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010334327723.74"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1979-09", 
    "datePublishedReg": "1979-09-01", 
    "description": "A study of the circular dichroism of chlorine-containing guainolides has shown that a negative Cotton effect in the 260-nm region correlates with the trans-linkage of the lactone ring in acroptilin, hyrcanin, chlorohyssopifolin B, elegin, and biebsanin. It has been established that this nature of the linkage does not change on relactonization and hydrogenation. A chloromethylene substituent at C4 causes a bathochromic shift of the lactone Cotton effect.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf00565926", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1009660", 
        "issn": [
          "0009-3130", 
          "1573-8388"
        ], 
        "name": "Chemistry of Natural Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "15"
      }
    ], 
    "keywords": [
      "circular dichroism", 
      "dichroism", 
      "negative Cotton effect", 
      "lactone ring", 
      "Cotton effect", 
      "linkage", 
      "region", 
      "C4", 
      "relactonization", 
      "effect", 
      "shift", 
      "guaianolides", 
      "study", 
      "nature", 
      "ring", 
      "bathochromic shift", 
      "substituents", 
      "hydrogenation", 
      "acroptilin", 
      "chlorine-containing guainolides", 
      "guainolides", 
      "hyrcanin", 
      "chlorohyssopifolin B", 
      "elegin", 
      "chloromethylene substituent", 
      "lactone Cotton effect", 
      "chlorine-containing guaianolides"
    ], 
    "name": "Circular dichroism of some chlorine-containing guaianolides", 
    "pagination": "569-571", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1050907620"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00565926"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00565926", 
      "https://app.dimensions.ai/details/publication/pub.1050907620"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T17:54", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_136.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf00565926"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00565926'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00565926'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00565926'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00565926'


 

This table displays all metadata directly associated to this object as RDF triples.

113 TRIPLES      21 PREDICATES      55 URIs      45 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00565926 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 anzsrc-for:09
4 anzsrc-for:0904
5 schema:author Nebff46c6a8b347adb2b4cfe0ffeb1634
6 schema:datePublished 1979-09
7 schema:datePublishedReg 1979-09-01
8 schema:description A study of the circular dichroism of chlorine-containing guainolides has shown that a negative Cotton effect in the 260-nm region correlates with the trans-linkage of the lactone ring in acroptilin, hyrcanin, chlorohyssopifolin B, elegin, and biebsanin. It has been established that this nature of the linkage does not change on relactonization and hydrogenation. A chloromethylene substituent at C4 causes a bathochromic shift of the lactone Cotton effect.
9 schema:genre article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N1b8115f2391a42cc84dca7e6ec8bb7e4
13 N6ee687ab8dc2436085fb1b07e4193108
14 sg:journal.1009660
15 schema:keywords C4
16 Cotton effect
17 acroptilin
18 bathochromic shift
19 chlorine-containing guaianolides
20 chlorine-containing guainolides
21 chlorohyssopifolin B
22 chloromethylene substituent
23 circular dichroism
24 dichroism
25 effect
26 elegin
27 guaianolides
28 guainolides
29 hydrogenation
30 hyrcanin
31 lactone Cotton effect
32 lactone ring
33 linkage
34 nature
35 negative Cotton effect
36 region
37 relactonization
38 ring
39 shift
40 study
41 substituents
42 schema:name Circular dichroism of some chlorine-containing guaianolides
43 schema:pagination 569-571
44 schema:productId Nc87d614afef8434b8ff05c6caa634b2b
45 Nf54eb862b1f646e98d897cd54681cafa
46 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050907620
47 https://doi.org/10.1007/bf00565926
48 schema:sdDatePublished 2021-11-01T17:54
49 schema:sdLicense https://scigraph.springernature.com/explorer/license/
50 schema:sdPublisher Nef324dc5b814456abe10188d640197d9
51 schema:url https://doi.org/10.1007/bf00565926
52 sgo:license sg:explorer/license/
53 sgo:sdDataset articles
54 rdf:type schema:ScholarlyArticle
55 N1b8115f2391a42cc84dca7e6ec8bb7e4 schema:volumeNumber 15
56 rdf:type schema:PublicationVolume
57 N3a6afdd4ad1341ab8fd2cd35fdeea73a rdf:first sg:person.010334327723.74
58 rdf:rest rdf:nil
59 N3d9fce2c29014e969d7d6b1d9ae8c22d rdf:first sg:person.012374162176.65
60 rdf:rest N6190154141c544c2a771c1622c03672f
61 N6190154141c544c2a771c1622c03672f rdf:first sg:person.010225514060.51
62 rdf:rest Na53f5d9474bc46cab663d4dd7c17963a
63 N6ee687ab8dc2436085fb1b07e4193108 schema:issueNumber 5
64 rdf:type schema:PublicationIssue
65 Na53f5d9474bc46cab663d4dd7c17963a rdf:first sg:person.010760410113.88
66 rdf:rest N3a6afdd4ad1341ab8fd2cd35fdeea73a
67 Nc87d614afef8434b8ff05c6caa634b2b schema:name dimensions_id
68 schema:value pub.1050907620
69 rdf:type schema:PropertyValue
70 Nebff46c6a8b347adb2b4cfe0ffeb1634 rdf:first sg:person.013736062563.28
71 rdf:rest N3d9fce2c29014e969d7d6b1d9ae8c22d
72 Nef324dc5b814456abe10188d640197d9 schema:name Springer Nature - SN SciGraph project
73 rdf:type schema:Organization
74 Nf54eb862b1f646e98d897cd54681cafa schema:name doi
75 schema:value 10.1007/bf00565926
76 rdf:type schema:PropertyValue
77 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
78 schema:name Chemical Sciences
79 rdf:type schema:DefinedTerm
80 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
81 schema:name Organic Chemistry
82 rdf:type schema:DefinedTerm
83 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
84 schema:name Engineering
85 rdf:type schema:DefinedTerm
86 anzsrc-for:0904 schema:inDefinedTermSet anzsrc-for:
87 schema:name Chemical Engineering
88 rdf:type schema:DefinedTerm
89 sg:journal.1009660 schema:issn 0009-3130
90 1573-8388
91 schema:name Chemistry of Natural Compounds
92 schema:publisher Springer Nature
93 rdf:type schema:Periodical
94 sg:person.010225514060.51 schema:familyName Mallabaev
95 schema:givenName A.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010225514060.51
97 rdf:type schema:Person
98 sg:person.010334327723.74 schema:familyName Sidyakin
99 schema:givenName G. P.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010334327723.74
101 rdf:type schema:Person
102 sg:person.010760410113.88 schema:familyName Yagudaev
103 schema:givenName M. R.
104 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010760410113.88
105 rdf:type schema:Person
106 sg:person.012374162176.65 schema:familyName Sham'yanov
107 schema:givenName I. D.
108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012374162176.65
109 rdf:type schema:Person
110 sg:person.013736062563.28 schema:familyName Moiseeva
111 schema:givenName G. P.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013736062563.28
113 rdf:type schema:Person
 




Preview window. Press ESC to close (or click here)


...