Synthesis of 2-alkylthio-5-acetyl-2-oxazolines View Full Text


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Article Info

DATE

1980-04

AUTHORS

O. N. Bubel', I. G. Tishchenko, O. A. Grinkevich, A. F. Abramov

ABSTRACT

The reaction of 2-acetyloxiranes with alkyl thiocyanates in the presence of Lewis acids (BF3, AlCl3) has given 2-alkylthio-5-acetyl-2-oxazolines (yields 40–60%). It has been shown that the reaction of trans-2-acetyl-3-methyloxirane and of trans-2-acetyl-3-methyloxirane and of trans-2-acetyl-2,3-dimethyloxirane with alkyl thiocyanates takes place stereospecifically and leads to cis-2-alkylthio-5-acetyl-2-oxazolines.

PAGES

352-355

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00552772

DOI

http://dx.doi.org/10.1007/bf00552772

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049969685


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