The lattice constants of a-quartz View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1980-01

AUTHORS

J. C. Brice

ABSTRACT

Data relating to the lattice constants of quartz are reviewed and it is shown that hydrogen and most other impurities increase the a lattice constant and decrease the axial ratio c/a. The available data can be described by c/a=1.10013−0.20 (a−a0) where a0 is the lattice constant of the pure material. The values of a0 at 25° C are deduced to be 4.9127 and 4.9134 Å, respectively, for natural and synthetic quartz with uncertainties in the last figure of about 1. This difference cannot be attributed to the large hydrogen content of the synthetic quartz since it is shown that this has a negligible effect on a. Neither is it due to differences of growth mechanism since crystals of synthetic quartz grown on different faces behave identically. Thus the differences between natural and synthetic quartz must be attributed to differences in the growth conditions (temperature, pressure and mineralizer). This attribution can account for the spread of natural quartz data. Values of the cell parameters are suggested which allow interplanar and Bragg angles to be calculated with uncertainties of between 0.001 and 0.003°. Thus for decreasingly pure grades of quartz, natural quartz has a rising from 4.9129 to 4.9138 Å associated with a fall of c/a from 1.10012 to 1.10004. Uncertainties in the a values range from 2×10−4 to 5×10−4 Å and uncertainties in the c/a ratio range from 4×10−5 to 12×10−5. More... »

PAGES

161-167

Journal

TITLE

Journal of Materials Science

ISSUE

1

VOLUME

15

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00552441

DOI

http://dx.doi.org/10.1007/bf00552441

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048725334


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Philips (United Kingdom)", 
          "id": "https://www.grid.ac/institutes/grid.423555.0", 
          "name": [
            "Philips Research Laboratories, Redhill, Surrey, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Brice", 
        "givenName": "J. C.", 
        "id": "sg:person.014703244407.26", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014703244407.26"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1107/s0365110x65001640", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016160343"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0567739478001242", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022172818"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0365110x65001639", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022541401"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0567740869003220", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024596087"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-0248(73)90139-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037570727"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-0248(73)90139-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037570727"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0021889876011187", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043473493"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1098/rspa.1933.0165", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047333964"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0034-4885/40/5/002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048005629"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0021889874010211", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052679141"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0370-1301/63/3/307", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1059091920"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrev.109.1467", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060419887"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrev.109.1467", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060419887"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrev.110.1060", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060420239"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrev.110.1060", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060420239"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1109/jrproc.1962.288222", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1061315440"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1109/freq.1978.200255", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1086221082"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1109/freq.1978.200253", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1086253666"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1109/freq.1978.200254", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1086255199"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1980-01", 
    "datePublishedReg": "1980-01-01", 
    "description": "Data relating to the lattice constants of quartz are reviewed and it is shown that hydrogen and most other impurities increase the a lattice constant and decrease the axial ratio c/a. The available data can be described by c/a=1.10013\u22120.20 (a\u2212a0) where a0 is the lattice constant of the pure material. The values of a0 at 25\u00b0 C are deduced to be 4.9127 and 4.9134 \u00c5, respectively, for natural and synthetic quartz with uncertainties in the last figure of about 1. This difference cannot be attributed to the large hydrogen content of the synthetic quartz since it is shown that this has a negligible effect on a. Neither is it due to differences of growth mechanism since crystals of synthetic quartz grown on different faces behave identically. Thus the differences between natural and synthetic quartz must be attributed to differences in the growth conditions (temperature, pressure and mineralizer). This attribution can account for the spread of natural quartz data. Values of the cell parameters are suggested which allow interplanar and Bragg angles to be calculated with uncertainties of between 0.001 and 0.003\u00b0. Thus for decreasingly pure grades of quartz, natural quartz has a rising from 4.9129 to 4.9138 \u00c5 associated with a fall of c/a from 1.10012 to 1.10004. Uncertainties in the a values range from 2\u00d710\u22124 to 5\u00d710\u22124 \u00c5 and uncertainties in the c/a ratio range from 4\u00d710\u22125 to 12\u00d710\u22125.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00552441", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1312116", 
        "issn": [
          "0022-2461", 
          "1573-4811"
        ], 
        "name": "Journal of Materials Science", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "15"
      }
    ], 
    "name": "The lattice constants of a-quartz", 
    "pagination": "161-167", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "e81e536167ad6d2d442afb4ce649250b7c50c1411a869b38f32d83837be7f491"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00552441"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1048725334"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00552441", 
      "https://app.dimensions.ai/details/publication/pub.1048725334"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:51", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000371_0000000371/records_130801_00000004.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/BF00552441"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00552441'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00552441'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00552441'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00552441'


 

This table displays all metadata directly associated to this object as RDF triples.

109 TRIPLES      21 PREDICATES      43 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00552441 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N24840f4c51804a5ab06cded36a837a0d
4 schema:citation https://doi.org/10.1016/0022-0248(73)90139-5
5 https://doi.org/10.1088/0034-4885/40/5/002
6 https://doi.org/10.1088/0370-1301/63/3/307
7 https://doi.org/10.1098/rspa.1933.0165
8 https://doi.org/10.1103/physrev.109.1467
9 https://doi.org/10.1103/physrev.110.1060
10 https://doi.org/10.1107/s0021889874010211
11 https://doi.org/10.1107/s0021889876011187
12 https://doi.org/10.1107/s0365110x65001639
13 https://doi.org/10.1107/s0365110x65001640
14 https://doi.org/10.1107/s0567739478001242
15 https://doi.org/10.1107/s0567740869003220
16 https://doi.org/10.1109/freq.1978.200253
17 https://doi.org/10.1109/freq.1978.200254
18 https://doi.org/10.1109/freq.1978.200255
19 https://doi.org/10.1109/jrproc.1962.288222
20 schema:datePublished 1980-01
21 schema:datePublishedReg 1980-01-01
22 schema:description Data relating to the lattice constants of quartz are reviewed and it is shown that hydrogen and most other impurities increase the a lattice constant and decrease the axial ratio c/a. The available data can be described by c/a=1.10013−0.20 (a−a0) where a0 is the lattice constant of the pure material. The values of a0 at 25° C are deduced to be 4.9127 and 4.9134 Å, respectively, for natural and synthetic quartz with uncertainties in the last figure of about 1. This difference cannot be attributed to the large hydrogen content of the synthetic quartz since it is shown that this has a negligible effect on a. Neither is it due to differences of growth mechanism since crystals of synthetic quartz grown on different faces behave identically. Thus the differences between natural and synthetic quartz must be attributed to differences in the growth conditions (temperature, pressure and mineralizer). This attribution can account for the spread of natural quartz data. Values of the cell parameters are suggested which allow interplanar and Bragg angles to be calculated with uncertainties of between 0.001 and 0.003°. Thus for decreasingly pure grades of quartz, natural quartz has a rising from 4.9129 to 4.9138 Å associated with a fall of c/a from 1.10012 to 1.10004. Uncertainties in the a values range from 2×10−4 to 5×10−4 Å and uncertainties in the c/a ratio range from 4×10−5 to 12×10−5.
23 schema:genre research_article
24 schema:inLanguage en
25 schema:isAccessibleForFree false
26 schema:isPartOf N2fc684686ef940b09d0a8d97150fe66e
27 N61f83a946f8e4c6989e455064cce8b85
28 sg:journal.1312116
29 schema:name The lattice constants of a-quartz
30 schema:pagination 161-167
31 schema:productId N01d781305b4c434aafb522b6264b64d8
32 N324e1360a64444349d032ed2d01b7773
33 Nb7297662c96c4b5cbcf858b5b5d70bb2
34 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048725334
35 https://doi.org/10.1007/bf00552441
36 schema:sdDatePublished 2019-04-11T13:51
37 schema:sdLicense https://scigraph.springernature.com/explorer/license/
38 schema:sdPublisher N53874a16eec04e5b8df2c5af7897bc6e
39 schema:url http://link.springer.com/10.1007/BF00552441
40 sgo:license sg:explorer/license/
41 sgo:sdDataset articles
42 rdf:type schema:ScholarlyArticle
43 N01d781305b4c434aafb522b6264b64d8 schema:name doi
44 schema:value 10.1007/bf00552441
45 rdf:type schema:PropertyValue
46 N24840f4c51804a5ab06cded36a837a0d rdf:first sg:person.014703244407.26
47 rdf:rest rdf:nil
48 N2fc684686ef940b09d0a8d97150fe66e schema:volumeNumber 15
49 rdf:type schema:PublicationVolume
50 N324e1360a64444349d032ed2d01b7773 schema:name dimensions_id
51 schema:value pub.1048725334
52 rdf:type schema:PropertyValue
53 N53874a16eec04e5b8df2c5af7897bc6e schema:name Springer Nature - SN SciGraph project
54 rdf:type schema:Organization
55 N61f83a946f8e4c6989e455064cce8b85 schema:issueNumber 1
56 rdf:type schema:PublicationIssue
57 Nb7297662c96c4b5cbcf858b5b5d70bb2 schema:name readcube_id
58 schema:value e81e536167ad6d2d442afb4ce649250b7c50c1411a869b38f32d83837be7f491
59 rdf:type schema:PropertyValue
60 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
61 schema:name Chemical Sciences
62 rdf:type schema:DefinedTerm
63 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
64 schema:name Organic Chemistry
65 rdf:type schema:DefinedTerm
66 sg:journal.1312116 schema:issn 0022-2461
67 1573-4811
68 schema:name Journal of Materials Science
69 rdf:type schema:Periodical
70 sg:person.014703244407.26 schema:affiliation https://www.grid.ac/institutes/grid.423555.0
71 schema:familyName Brice
72 schema:givenName J. C.
73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014703244407.26
74 rdf:type schema:Person
75 https://doi.org/10.1016/0022-0248(73)90139-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037570727
76 rdf:type schema:CreativeWork
77 https://doi.org/10.1088/0034-4885/40/5/002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048005629
78 rdf:type schema:CreativeWork
79 https://doi.org/10.1088/0370-1301/63/3/307 schema:sameAs https://app.dimensions.ai/details/publication/pub.1059091920
80 rdf:type schema:CreativeWork
81 https://doi.org/10.1098/rspa.1933.0165 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047333964
82 rdf:type schema:CreativeWork
83 https://doi.org/10.1103/physrev.109.1467 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060419887
84 rdf:type schema:CreativeWork
85 https://doi.org/10.1103/physrev.110.1060 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060420239
86 rdf:type schema:CreativeWork
87 https://doi.org/10.1107/s0021889874010211 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052679141
88 rdf:type schema:CreativeWork
89 https://doi.org/10.1107/s0021889876011187 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043473493
90 rdf:type schema:CreativeWork
91 https://doi.org/10.1107/s0365110x65001639 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022541401
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1107/s0365110x65001640 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016160343
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1107/s0567739478001242 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022172818
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1107/s0567740869003220 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024596087
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1109/freq.1978.200253 schema:sameAs https://app.dimensions.ai/details/publication/pub.1086253666
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1109/freq.1978.200254 schema:sameAs https://app.dimensions.ai/details/publication/pub.1086255199
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1109/freq.1978.200255 schema:sameAs https://app.dimensions.ai/details/publication/pub.1086221082
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1109/jrproc.1962.288222 schema:sameAs https://app.dimensions.ai/details/publication/pub.1061315440
106 rdf:type schema:CreativeWork
107 https://www.grid.ac/institutes/grid.423555.0 schema:alternateName Philips (United Kingdom)
108 schema:name Philips Research Laboratories, Redhill, Surrey, UK
109 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...