Preparation and properties of HZr2P3O12 and related compounds View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1984-08

AUTHORS

Akira Ono

ABSTRACT

HZr2P3O12 (H-form) was prepared in air at 650° C by de-ammoniation of NH4Zr2P3O12 (NH4-form) in order to study properties of proton in the NaZr2P3O12-type structure. Hydration of H-form took place at 70° C, 0.15 GPa, and the final product is (H3O)Zr2P3O12·O·17H2O (H3O-form). H- and H3O-forms reacted with alkali chloride solutions at 25° C. Rates of the exchange reactions were studied as a function of water content of H- and H3O-bearing compounds. The H-form showed an excellent selectivity for univalent cations in the order: ammonium < potassium < rubidium ≪ sodium, lithium. More... »

PAGES

2691-2695

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00550826

DOI

http://dx.doi.org/10.1007/bf00550826

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041732340


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