Kinetics of α- and β-Si3N4 formation from oxide-free high-purity Si powder View Full Text


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Article Info

DATE

1991-01-01

AUTHORS

A. Varma, R. G. Pigeon, A. E. Miller

ABSTRACT

Available kinetic data for the nitridation of high-purity oxide-free Si powder are analysed. The analysis suggests that the α- and β-phases of Si3N4 are formed by separate and parallel reaction paths, and kinetic expressions for their formation are reported. The formation of the α-phase follows first-order kinetics, while the β-phase is formed by a phase-boundary-controlled rate law. These conclusions are consistent with other kinetic and micrographic analyses reported in the literature. More... »

PAGES

4541-4544

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00543678

DOI

http://dx.doi.org/10.1007/bf00543678

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005884942


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