The influence of carbon on nitrogen substitution in iron ε -phases View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1982-06

AUTHORS

D. Firrao, M. Rosso, G. Principi, R. Frattini

ABSTRACT

Mössbauer spectroscopy of nitrided and carbonitrided iron powders and plates with total interstitial atom contents of between 24 and 33 at% has allowed the variation with composition of the hyperfine magnetic fields of metal atoms with 2 or 3 close interstitial atoms to be determined. Fe atoms with three non-metal nearest neighbours and paramagnetic behaviour have also been detected. Only when the content of non-metal atoms goes beyond 30 at%, do Fe atoms in ε-carbonitrides display higher magnetic fields than in the corresponding ε-nitrides. The lower number of electrons contributed to the iron 3d-orbitals by C atoms than by N atoms is considered the cause of the above phenomenon. The variation of other hyperfine parameters with composition is also discussed. More... »

PAGES

1773-1788

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00540806

DOI

http://dx.doi.org/10.1007/bf00540806

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1001915239


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