Charge distribution and 13C NMR spectra of cyanine dyes with bridging groupings in the chromophore View Full Text


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Article Info

DATE

1988-11

AUTHORS

Yu. L. Slominskii, S. V. Popov, I. V. Repyakh, M. I. Povolotskii, A. D. Kachkovskii, G. G. Dyadyusha

ABSTRACT

The electronic structure of cationoid and anionoid cyanine dyes was calculated by the CNDO/2 method. The calculation results were compared with the data of the 13C NMR spectra. It was shown that the anionoid dyes of the malonocyanine class have all the inherent properties of a polymethine state, i.e., alternation of charges and leveling of bonds, and these are also characteristic of cationic streptopolymethines. According to the calculation data, the introduction of bridging groupings causes considerable changes in the electronic structure of the cyanine dyes, as confirmed by the results of the study of their 13C NMR spectra. More... »

PAGES

635-639

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00534604

DOI

http://dx.doi.org/10.1007/bf00534604

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042521159


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