Problem of ambivalence in organic reactions View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1988-05

AUTHORS

S. V. Volovik

ABSTRACT

A “pure“ model of intermolecular ambivalence (nucleophilic-electrophilic dichotomy) in organic reactions was developed within the bounds of a qualitative analysis of interactions of diabatic potential energy surfaces and frontier MO for an attacking reagent-substrate system. The chemical aspects of this phenomenon and the limits of its occurrence, as well as the possible limitations of the model and the range of its potential applications are discussed. The concept of the immanent ambivalence of electronic systems has been introduced. More... »

PAGES

268-274

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00534551

DOI

http://dx.doi.org/10.1007/bf00534551

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026935388


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