1988-05
AUTHORS ABSTRACTA “pure“ model of intermolecular ambivalence (nucleophilic-electrophilic dichotomy) in organic reactions was developed within the bounds of a qualitative analysis of interactions of diabatic potential energy surfaces and frontier MO for an attacking reagent-substrate system. The chemical aspects of this phenomenon and the limits of its occurrence, as well as the possible limitations of the model and the range of its potential applications are discussed. The concept of the immanent ambivalence of electronic systems has been introduced. More... »
PAGES268-274
http://scigraph.springernature.com/pub.10.1007/bf00534551
DOIhttp://dx.doi.org/10.1007/bf00534551
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