Reaction of 6-oxo-, thioxo-2,3-dimethylthieno[2,3-d]pyrimidin-4-ones with electrophelic reagents View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-11

AUTHORS

M. Shodiev, B. A. Urakov, N. I. Mukarramov, Kh. M. Shakhidoyatov

ABSTRACT

The reaction of 6-oxo-, thioxo-2,3-dimethylthieno[2,3-d]pyrimidin-4-ones with electrophilic agents was studied. It was shown that during nitration these compounds undergo electrophilic unco-substitution forming 3-nitro- and 2-nitro-6-oxo- and 2,3-dinitro-6-thioxothieno[2,3-d]pyrimidin-4-ones, respectively; the reaction of these compounds with bromine proceeds in other directions.

PAGES

1358-1360

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00532040

DOI

http://dx.doi.org/10.1007/bf00532040

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1046653378


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Chemistry of Plant Materials, Academy of Sciences of Republic of Uzbekistan, 700170, Tashkent", 
          "id": "http://www.grid.ac/institutes/grid.419209.7", 
          "name": [
            "Institute of Chemistry of Plant Materials, Academy of Sciences of Republic of Uzbekistan, 700170, Tashkent"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shodiev", 
        "givenName": "M.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemistry of Plant Materials, Academy of Sciences of Republic of Uzbekistan, 700170, Tashkent", 
          "id": "http://www.grid.ac/institutes/grid.419209.7", 
          "name": [
            "Institute of Chemistry of Plant Materials, Academy of Sciences of Republic of Uzbekistan, 700170, Tashkent"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Urakov", 
        "givenName": "B. A.", 
        "id": "sg:person.011050426407.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011050426407.16"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemistry of Plant Materials, Academy of Sciences of Republic of Uzbekistan, 700170, Tashkent", 
          "id": "http://www.grid.ac/institutes/grid.419209.7", 
          "name": [
            "Institute of Chemistry of Plant Materials, Academy of Sciences of Republic of Uzbekistan, 700170, Tashkent"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mukarramov", 
        "givenName": "N. I.", 
        "id": "sg:person.012565645653.22", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012565645653.22"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemistry of Plant Materials, Academy of Sciences of Republic of Uzbekistan, 700170, Tashkent", 
          "id": "http://www.grid.ac/institutes/grid.419209.7", 
          "name": [
            "Institute of Chemistry of Plant Materials, Academy of Sciences of Republic of Uzbekistan, 700170, Tashkent"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shakhidoyatov", 
        "givenName": "Kh. M.", 
        "id": "sg:person.015706066705.62", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015706066705.62"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1993-11", 
    "datePublishedReg": "1993-11-01", 
    "description": "The reaction of 6-oxo-, thioxo-2,3-dimethylthieno[2,3-d]pyrimidin-4-ones with electrophilic agents was studied. It was shown that during nitration these compounds undergo electrophilic unco-substitution forming 3-nitro- and 2-nitro-6-oxo- and 2,3-dinitro-6-thioxothieno[2,3-d]pyrimidin-4-ones, respectively; the reaction of these compounds with bromine proceeds in other directions.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf00532040", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1358699", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "11", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "29"
      }
    ], 
    "keywords": [
      "electrophilic agents", 
      "reaction", 
      "compounds", 
      "reagents", 
      "nitration", 
      "proceeds", 
      "agents", 
      "direction", 
      "electrophilic unco-substitution", 
      "unco-substitution", 
      "bromine proceeds", 
      "electrophelic reagents"
    ], 
    "name": "Reaction of 6-oxo-, thioxo-2,3-dimethylthieno[2,3-d]pyrimidin-4-ones with electrophelic reagents", 
    "pagination": "1358-1360", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1046653378"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00532040"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00532040", 
      "https://app.dimensions.ai/details/publication/pub.1046653378"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T17:59", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_234.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf00532040"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00532040'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00532040'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00532040'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00532040'


 

This table displays all metadata directly associated to this object as RDF triples.

90 TRIPLES      21 PREDICATES      38 URIs      30 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00532040 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N86485f7e3f7c42b4bcf4cdcbdf720d81
4 schema:datePublished 1993-11
5 schema:datePublishedReg 1993-11-01
6 schema:description The reaction of 6-oxo-, thioxo-2,3-dimethylthieno[2,3-d]pyrimidin-4-ones with electrophilic agents was studied. It was shown that during nitration these compounds undergo electrophilic unco-substitution forming 3-nitro- and 2-nitro-6-oxo- and 2,3-dinitro-6-thioxothieno[2,3-d]pyrimidin-4-ones, respectively; the reaction of these compounds with bromine proceeds in other directions.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N6effe30e538848eaa3f2d02485591202
11 Nc749d59a484645f5ae1c04733b46bc77
12 sg:journal.1358699
13 schema:keywords agents
14 bromine proceeds
15 compounds
16 direction
17 electrophelic reagents
18 electrophilic agents
19 electrophilic unco-substitution
20 nitration
21 proceeds
22 reaction
23 reagents
24 unco-substitution
25 schema:name Reaction of 6-oxo-, thioxo-2,3-dimethylthieno[2,3-d]pyrimidin-4-ones with electrophelic reagents
26 schema:pagination 1358-1360
27 schema:productId N4f84747d4d744247a000ddab50adfaa3
28 Nf0d6aae40bca41d4bd437ee1cd1dd450
29 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046653378
30 https://doi.org/10.1007/bf00532040
31 schema:sdDatePublished 2021-11-01T17:59
32 schema:sdLicense https://scigraph.springernature.com/explorer/license/
33 schema:sdPublisher N550ebe00777046a29431f6eb5da9ca3b
34 schema:url https://doi.org/10.1007/bf00532040
35 sgo:license sg:explorer/license/
36 sgo:sdDataset articles
37 rdf:type schema:ScholarlyArticle
38 N4f84747d4d744247a000ddab50adfaa3 schema:name doi
39 schema:value 10.1007/bf00532040
40 rdf:type schema:PropertyValue
41 N550ebe00777046a29431f6eb5da9ca3b schema:name Springer Nature - SN SciGraph project
42 rdf:type schema:Organization
43 N63ff9e722c8f4a2286774d0e2cd2a468 rdf:first sg:person.012565645653.22
44 rdf:rest Nd1bc2f85998f4c04a112f92530f80d2f
45 N6effe30e538848eaa3f2d02485591202 schema:volumeNumber 29
46 rdf:type schema:PublicationVolume
47 N85164f730caa4c79bcdd61a85d16ec08 rdf:first sg:person.011050426407.16
48 rdf:rest N63ff9e722c8f4a2286774d0e2cd2a468
49 N86485f7e3f7c42b4bcf4cdcbdf720d81 rdf:first Nf3d267a4dd594def87ca1853dc7753fc
50 rdf:rest N85164f730caa4c79bcdd61a85d16ec08
51 Nc749d59a484645f5ae1c04733b46bc77 schema:issueNumber 11
52 rdf:type schema:PublicationIssue
53 Nd1bc2f85998f4c04a112f92530f80d2f rdf:first sg:person.015706066705.62
54 rdf:rest rdf:nil
55 Nf0d6aae40bca41d4bd437ee1cd1dd450 schema:name dimensions_id
56 schema:value pub.1046653378
57 rdf:type schema:PropertyValue
58 Nf3d267a4dd594def87ca1853dc7753fc schema:affiliation grid-institutes:grid.419209.7
59 schema:familyName Shodiev
60 schema:givenName M.
61 rdf:type schema:Person
62 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
63 schema:name Chemical Sciences
64 rdf:type schema:DefinedTerm
65 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
66 schema:name Organic Chemistry
67 rdf:type schema:DefinedTerm
68 sg:journal.1358699 schema:issn 0132-6244
69 1573-8353
70 schema:name Chemistry of Heterocyclic Compounds
71 schema:publisher Springer Nature
72 rdf:type schema:Periodical
73 sg:person.011050426407.16 schema:affiliation grid-institutes:grid.419209.7
74 schema:familyName Urakov
75 schema:givenName B. A.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011050426407.16
77 rdf:type schema:Person
78 sg:person.012565645653.22 schema:affiliation grid-institutes:grid.419209.7
79 schema:familyName Mukarramov
80 schema:givenName N. I.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012565645653.22
82 rdf:type schema:Person
83 sg:person.015706066705.62 schema:affiliation grid-institutes:grid.419209.7
84 schema:familyName Shakhidoyatov
85 schema:givenName Kh. M.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015706066705.62
87 rdf:type schema:Person
88 grid-institutes:grid.419209.7 schema:alternateName Institute of Chemistry of Plant Materials, Academy of Sciences of Republic of Uzbekistan, 700170, Tashkent
89 schema:name Institute of Chemistry of Plant Materials, Academy of Sciences of Republic of Uzbekistan, 700170, Tashkent
90 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...