Catalytic properties of trinuclear thio complexes of rhenium in hydrogenation of m-nitrobenzoic acid View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-05

AUTHORS

V. M. Belousov, T. A. Pal'chevskaya, S. V. Volkov, V. L. Kolesnichenko, L. V. Bogutskaya, S. P. Sharavskaya

ABSTRACT

Trinuclear thio complexes of rhenium based on Re3S7 and Re3S4 cluster groupings have been synthesized and studied as catalysts in liquid-phase hydrogenation of m-nitrobenzoic acid. Thio complexes containing as Re3S7 cluster surrounded by hydroxo groups are the most active. Complexes with an Re3S4 cluster are less active. Reversible Re3S7 ⇆ Re3S4 + S8 transitions were found to be possible in solution. More... »

PAGES

194-196

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00529418

DOI

http://dx.doi.org/10.1007/bf00529418

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013080955


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0399", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev", 
          "id": "http://www.grid.ac/institutes/grid.469987.d", 
          "name": [
            "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Belousov", 
        "givenName": "V. M.", 
        "id": "sg:person.012403673763.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012403673763.27"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev", 
          "id": "http://www.grid.ac/institutes/grid.469987.d", 
          "name": [
            "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pal'chevskaya", 
        "givenName": "T. A.", 
        "id": "sg:person.013261205477.82", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013261205477.82"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev", 
          "id": "http://www.grid.ac/institutes/grid.469987.d", 
          "name": [
            "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Volkov", 
        "givenName": "S. V.", 
        "id": "sg:person.0777572327.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0777572327.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev", 
          "id": "http://www.grid.ac/institutes/grid.469987.d", 
          "name": [
            "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kolesnichenko", 
        "givenName": "V. L.", 
        "id": "sg:person.01220212030.98", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01220212030.98"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev", 
          "id": "http://www.grid.ac/institutes/grid.469987.d", 
          "name": [
            "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bogutskaya", 
        "givenName": "L. V.", 
        "id": "sg:person.014035406137.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014035406137.29"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev", 
          "id": "http://www.grid.ac/institutes/grid.469987.d", 
          "name": [
            "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sharavskaya", 
        "givenName": "S. P.", 
        "id": "sg:person.011205112477.14", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011205112477.14"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1993-05", 
    "datePublishedReg": "1993-05-01", 
    "description": "Trinuclear thio complexes of rhenium based on Re3S7 and Re3S4 cluster groupings have been synthesized and studied as catalysts in liquid-phase hydrogenation of m-nitrobenzoic acid. Thio complexes containing as Re3S7 cluster surrounded by hydroxo groups are the most active. Complexes with an Re3S4 cluster are less active. Reversible Re3S7 \u21c6 Re3S4 + S8 transitions were found to be possible in solution.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf00529418", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1010993", 
        "issn": [
          "0040-5760", 
          "1573-935X"
        ], 
        "name": "Theoretical and Experimental Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "28"
      }
    ], 
    "keywords": [
      "thio complexes", 
      "liquid-phase hydrogenation", 
      "nitrobenzoic acid", 
      "hydroxo groups", 
      "catalytic properties", 
      "hydrogenation", 
      "complexes", 
      "rhenium", 
      "catalyst", 
      "acid", 
      "properties", 
      "clusters", 
      "solution", 
      "transition", 
      "group", 
      "grouping", 
      "cluster groupings", 
      "Re3S7", 
      "Re3S4 cluster groupings", 
      "Re3S7 cluster", 
      "Re3S4 cluster", 
      "Reversible Re3S7", 
      "Re3S4", 
      "S8 transitions", 
      "trinuclear thio complexes"
    ], 
    "name": "Catalytic properties of trinuclear thio complexes of rhenium in hydrogenation of m-nitrobenzoic acid", 
    "pagination": "194-196", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1013080955"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00529418"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00529418", 
      "https://app.dimensions.ai/details/publication/pub.1013080955"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T17:59", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_236.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf00529418"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00529418'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00529418'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00529418'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00529418'


 

This table displays all metadata directly associated to this object as RDF triples.

126 TRIPLES      21 PREDICATES      53 URIs      43 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00529418 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 anzsrc-for:0306
4 anzsrc-for:0399
5 schema:author N61f6232d964f40de9954a36a8a6c3dec
6 schema:datePublished 1993-05
7 schema:datePublishedReg 1993-05-01
8 schema:description Trinuclear thio complexes of rhenium based on Re3S7 and Re3S4 cluster groupings have been synthesized and studied as catalysts in liquid-phase hydrogenation of m-nitrobenzoic acid. Thio complexes containing as Re3S7 cluster surrounded by hydroxo groups are the most active. Complexes with an Re3S4 cluster are less active. Reversible Re3S7 ⇆ Re3S4 + S8 transitions were found to be possible in solution.
9 schema:genre article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N57a99a4b3ed54abb87320d6a04b67e86
13 Nea29ba0bd78d4d03838fa4bc80f1ae7c
14 sg:journal.1010993
15 schema:keywords Re3S4
16 Re3S4 cluster
17 Re3S4 cluster groupings
18 Re3S7
19 Re3S7 cluster
20 Reversible Re3S7
21 S8 transitions
22 acid
23 catalyst
24 catalytic properties
25 cluster groupings
26 clusters
27 complexes
28 group
29 grouping
30 hydrogenation
31 hydroxo groups
32 liquid-phase hydrogenation
33 nitrobenzoic acid
34 properties
35 rhenium
36 solution
37 thio complexes
38 transition
39 trinuclear thio complexes
40 schema:name Catalytic properties of trinuclear thio complexes of rhenium in hydrogenation of m-nitrobenzoic acid
41 schema:pagination 194-196
42 schema:productId N2f6773eabab149cabdca4df5e0485405
43 Ncb362c7897be41cf967744ee48b934a8
44 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013080955
45 https://doi.org/10.1007/bf00529418
46 schema:sdDatePublished 2021-11-01T17:59
47 schema:sdLicense https://scigraph.springernature.com/explorer/license/
48 schema:sdPublisher N6e648788e1ef4676be960887bd475b1f
49 schema:url https://doi.org/10.1007/bf00529418
50 sgo:license sg:explorer/license/
51 sgo:sdDataset articles
52 rdf:type schema:ScholarlyArticle
53 N068aee0e9f1842f0950eb3bf674273ca rdf:first sg:person.013261205477.82
54 rdf:rest Nd1ebf6e3a31e46b7a8fe02936c134411
55 N06cec05b1ab444e39e51cf099527c37f rdf:first sg:person.014035406137.29
56 rdf:rest Nd602fb63701443478d42b34ce16b3c26
57 N2f6773eabab149cabdca4df5e0485405 schema:name dimensions_id
58 schema:value pub.1013080955
59 rdf:type schema:PropertyValue
60 N447748114e8a465a8e466abb122a9e3d rdf:first sg:person.01220212030.98
61 rdf:rest N06cec05b1ab444e39e51cf099527c37f
62 N57a99a4b3ed54abb87320d6a04b67e86 schema:issueNumber 3
63 rdf:type schema:PublicationIssue
64 N61f6232d964f40de9954a36a8a6c3dec rdf:first sg:person.012403673763.27
65 rdf:rest N068aee0e9f1842f0950eb3bf674273ca
66 N6e648788e1ef4676be960887bd475b1f schema:name Springer Nature - SN SciGraph project
67 rdf:type schema:Organization
68 Ncb362c7897be41cf967744ee48b934a8 schema:name doi
69 schema:value 10.1007/bf00529418
70 rdf:type schema:PropertyValue
71 Nd1ebf6e3a31e46b7a8fe02936c134411 rdf:first sg:person.0777572327.37
72 rdf:rest N447748114e8a465a8e466abb122a9e3d
73 Nd602fb63701443478d42b34ce16b3c26 rdf:first sg:person.011205112477.14
74 rdf:rest rdf:nil
75 Nea29ba0bd78d4d03838fa4bc80f1ae7c schema:volumeNumber 28
76 rdf:type schema:PublicationVolume
77 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
78 schema:name Chemical Sciences
79 rdf:type schema:DefinedTerm
80 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
81 schema:name Inorganic Chemistry
82 rdf:type schema:DefinedTerm
83 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
84 schema:name Physical Chemistry (incl. Structural)
85 rdf:type schema:DefinedTerm
86 anzsrc-for:0399 schema:inDefinedTermSet anzsrc-for:
87 schema:name Other Chemical Sciences
88 rdf:type schema:DefinedTerm
89 sg:journal.1010993 schema:issn 0040-5760
90 1573-935X
91 schema:name Theoretical and Experimental Chemistry
92 schema:publisher Springer Nature
93 rdf:type schema:Periodical
94 sg:person.011205112477.14 schema:affiliation grid-institutes:grid.469987.d
95 schema:familyName Sharavskaya
96 schema:givenName S. P.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011205112477.14
98 rdf:type schema:Person
99 sg:person.01220212030.98 schema:affiliation grid-institutes:grid.469987.d
100 schema:familyName Kolesnichenko
101 schema:givenName V. L.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01220212030.98
103 rdf:type schema:Person
104 sg:person.012403673763.27 schema:affiliation grid-institutes:grid.469987.d
105 schema:familyName Belousov
106 schema:givenName V. M.
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012403673763.27
108 rdf:type schema:Person
109 sg:person.013261205477.82 schema:affiliation grid-institutes:grid.469987.d
110 schema:familyName Pal'chevskaya
111 schema:givenName T. A.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013261205477.82
113 rdf:type schema:Person
114 sg:person.014035406137.29 schema:affiliation grid-institutes:grid.469987.d
115 schema:familyName Bogutskaya
116 schema:givenName L. V.
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014035406137.29
118 rdf:type schema:Person
119 sg:person.0777572327.37 schema:affiliation grid-institutes:grid.469987.d
120 schema:familyName Volkov
121 schema:givenName S. V.
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0777572327.37
123 rdf:type schema:Person
124 grid-institutes:grid.469987.d schema:alternateName L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev
125 schema:name L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev
126 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...