Catalytic properties of trinuclear thio complexes of rhenium in hydrogenation of m-nitrobenzoic acid View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-05

AUTHORS

V. M. Belousov, T. A. Pal'chevskaya, S. V. Volkov, V. L. Kolesnichenko, L. V. Bogutskaya, S. P. Sharavskaya

ABSTRACT

Trinuclear thio complexes of rhenium based on Re3S7 and Re3S4 cluster groupings have been synthesized and studied as catalysts in liquid-phase hydrogenation of m-nitrobenzoic acid. Thio complexes containing as Re3S7 cluster surrounded by hydroxo groups are the most active. Complexes with an Re3S4 cluster are less active. Reversible Re3S7 ⇆ Re3S4 + S8 transitions were found to be possible in solution. More... »

PAGES

194-196

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00529418

DOI

http://dx.doi.org/10.1007/bf00529418

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013080955


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "L.V.Pisarzhevskii Institute of Physical Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.469987.d", 
          "name": [
            "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Belousov", 
        "givenName": "V. M.", 
        "id": "sg:person.012403673763.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012403673763.27"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "L.V.Pisarzhevskii Institute of Physical Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.469987.d", 
          "name": [
            "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pal'chevskaya", 
        "givenName": "T. A.", 
        "id": "sg:person.013261205477.82", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013261205477.82"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "L.V.Pisarzhevskii Institute of Physical Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.469987.d", 
          "name": [
            "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Volkov", 
        "givenName": "S. V.", 
        "id": "sg:person.0777572327.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0777572327.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "L.V.Pisarzhevskii Institute of Physical Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.469987.d", 
          "name": [
            "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kolesnichenko", 
        "givenName": "V. L.", 
        "id": "sg:person.011621036745.36", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011621036745.36"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "L.V.Pisarzhevskii Institute of Physical Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.469987.d", 
          "name": [
            "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bogutskaya", 
        "givenName": "L. V.", 
        "id": "sg:person.014035406137.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014035406137.29"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "L.V.Pisarzhevskii Institute of Physical Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.469987.d", 
          "name": [
            "L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sharavskaya", 
        "givenName": "S. P.", 
        "id": "sg:person.011205112477.14", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011205112477.14"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0304-5102(90)85267-l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018873073"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1993-05", 
    "datePublishedReg": "1993-05-01", 
    "description": "Trinuclear thio complexes of rhenium based on Re3S7 and Re3S4 cluster groupings have been synthesized and studied as catalysts in liquid-phase hydrogenation of m-nitrobenzoic acid. Thio complexes containing as Re3S7 cluster surrounded by hydroxo groups are the most active. Complexes with an Re3S4 cluster are less active. Reversible Re3S7 \u21c6 Re3S4 + S8 transitions were found to be possible in solution.", 
    "genre": "non_research_article", 
    "id": "sg:pub.10.1007/bf00529418", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1010993", 
        "issn": [
          "0040-5760", 
          "1573-935X"
        ], 
        "name": "Theoretical and Experimental Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "28"
      }
    ], 
    "name": "Catalytic properties of trinuclear thio complexes of rhenium in hydrogenation of m-nitrobenzoic acid", 
    "pagination": "194-196", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "3e5099073097d0a9ed81cb45040909a81ec7a84e0a71a5a4de07606994a7d569"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00529418"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1013080955"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00529418", 
      "https://app.dimensions.ai/details/publication/pub.1013080955"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:51", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000371_0000000371/records_130801_00000001.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF00529418"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00529418'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00529418'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00529418'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00529418'


 

This table displays all metadata directly associated to this object as RDF triples.

99 TRIPLES      21 PREDICATES      28 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00529418 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N03f1c3c4f05846c3b6f6f4003ed8f40b
4 schema:citation https://doi.org/10.1016/0304-5102(90)85267-l
5 schema:datePublished 1993-05
6 schema:datePublishedReg 1993-05-01
7 schema:description Trinuclear thio complexes of rhenium based on Re3S7 and Re3S4 cluster groupings have been synthesized and studied as catalysts in liquid-phase hydrogenation of m-nitrobenzoic acid. Thio complexes containing as Re3S7 cluster surrounded by hydroxo groups are the most active. Complexes with an Re3S4 cluster are less active. Reversible Re3S7 ⇆ Re3S4 + S8 transitions were found to be possible in solution.
8 schema:genre non_research_article
9 schema:inLanguage en
10 schema:isAccessibleForFree false
11 schema:isPartOf N6f857f0703804107a93643171e72194a
12 Nf00bd1cb4bc54b9a9817f81387a8f4f4
13 sg:journal.1010993
14 schema:name Catalytic properties of trinuclear thio complexes of rhenium in hydrogenation of m-nitrobenzoic acid
15 schema:pagination 194-196
16 schema:productId N1601f20b595648a69006c7ebb42409b5
17 Na8562fc52ad848ebbbd6c9d2fe46f4e4
18 Nbf6672e01d60413295d0404f0a030aca
19 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013080955
20 https://doi.org/10.1007/bf00529418
21 schema:sdDatePublished 2019-04-11T13:51
22 schema:sdLicense https://scigraph.springernature.com/explorer/license/
23 schema:sdPublisher N5ae0c0e95ce342b5bda082bbaa99a56e
24 schema:url http://link.springer.com/10.1007%2FBF00529418
25 sgo:license sg:explorer/license/
26 sgo:sdDataset articles
27 rdf:type schema:ScholarlyArticle
28 N03f1c3c4f05846c3b6f6f4003ed8f40b rdf:first sg:person.012403673763.27
29 rdf:rest N38608fcd92534686893f622905912b72
30 N1601f20b595648a69006c7ebb42409b5 schema:name readcube_id
31 schema:value 3e5099073097d0a9ed81cb45040909a81ec7a84e0a71a5a4de07606994a7d569
32 rdf:type schema:PropertyValue
33 N257fadfe9f924c0c98904a19dd1f1841 rdf:first sg:person.014035406137.29
34 rdf:rest N744e5203b93c40a39f2487c2afe8f739
35 N38608fcd92534686893f622905912b72 rdf:first sg:person.013261205477.82
36 rdf:rest Na39827b30e32414d939e53fb931ef791
37 N5ae0c0e95ce342b5bda082bbaa99a56e schema:name Springer Nature - SN SciGraph project
38 rdf:type schema:Organization
39 N6f857f0703804107a93643171e72194a schema:issueNumber 3
40 rdf:type schema:PublicationIssue
41 N744e5203b93c40a39f2487c2afe8f739 rdf:first sg:person.011205112477.14
42 rdf:rest rdf:nil
43 N99ae87711c52486ba775372830e62083 rdf:first sg:person.011621036745.36
44 rdf:rest N257fadfe9f924c0c98904a19dd1f1841
45 Na39827b30e32414d939e53fb931ef791 rdf:first sg:person.0777572327.37
46 rdf:rest N99ae87711c52486ba775372830e62083
47 Na8562fc52ad848ebbbd6c9d2fe46f4e4 schema:name dimensions_id
48 schema:value pub.1013080955
49 rdf:type schema:PropertyValue
50 Nbf6672e01d60413295d0404f0a030aca schema:name doi
51 schema:value 10.1007/bf00529418
52 rdf:type schema:PropertyValue
53 Nf00bd1cb4bc54b9a9817f81387a8f4f4 schema:volumeNumber 28
54 rdf:type schema:PublicationVolume
55 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
56 schema:name Chemical Sciences
57 rdf:type schema:DefinedTerm
58 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
59 schema:name Inorganic Chemistry
60 rdf:type schema:DefinedTerm
61 sg:journal.1010993 schema:issn 0040-5760
62 1573-935X
63 schema:name Theoretical and Experimental Chemistry
64 rdf:type schema:Periodical
65 sg:person.011205112477.14 schema:affiliation https://www.grid.ac/institutes/grid.469987.d
66 schema:familyName Sharavskaya
67 schema:givenName S. P.
68 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011205112477.14
69 rdf:type schema:Person
70 sg:person.011621036745.36 schema:affiliation https://www.grid.ac/institutes/grid.469987.d
71 schema:familyName Kolesnichenko
72 schema:givenName V. L.
73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011621036745.36
74 rdf:type schema:Person
75 sg:person.012403673763.27 schema:affiliation https://www.grid.ac/institutes/grid.469987.d
76 schema:familyName Belousov
77 schema:givenName V. M.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012403673763.27
79 rdf:type schema:Person
80 sg:person.013261205477.82 schema:affiliation https://www.grid.ac/institutes/grid.469987.d
81 schema:familyName Pal'chevskaya
82 schema:givenName T. A.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013261205477.82
84 rdf:type schema:Person
85 sg:person.014035406137.29 schema:affiliation https://www.grid.ac/institutes/grid.469987.d
86 schema:familyName Bogutskaya
87 schema:givenName L. V.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014035406137.29
89 rdf:type schema:Person
90 sg:person.0777572327.37 schema:affiliation https://www.grid.ac/institutes/grid.469987.d
91 schema:familyName Volkov
92 schema:givenName S. V.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0777572327.37
94 rdf:type schema:Person
95 https://doi.org/10.1016/0304-5102(90)85267-l schema:sameAs https://app.dimensions.ai/details/publication/pub.1018873073
96 rdf:type schema:CreativeWork
97 https://www.grid.ac/institutes/grid.469987.d schema:alternateName L.V.Pisarzhevskii Institute of Physical Chemistry
98 schema:name L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev
99 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...