Properties and electronic structure of tetrahalogenocuprate (II)-complexes View Full Text


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Article Info

DATE

1963-01

AUTHORS

Claudio Furlani, Giorgio Morpurgo

ABSTRACT

Several salts containing the complex anions [CuCl4]= or [CuBr4]= have heen prepared, and their spectra have been measured and interpreted in terms of ligand-field theory. They exhibit a d-d band with \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$\tilde v_{max} $$ \end{document} about 8–9000 cm−1, and several well defined charge-transfer bands in the visible and near ultraviolet spectral range. Several experimental facts, supported by theoretical considerations, indicate that the structure of the [CuX4]= anions is not a truly tetrahedral, but a flattened tetrahedral one, of symmetry D2d. Details on the course of the endothermic solvolysis reactions which occur in polar organic solvents, and on the probable nature of the solvolysis products are reported and discussed. More... »

PAGES

102-115

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00529392

DOI

http://dx.doi.org/10.1007/bf00529392

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026197985


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