Dynamic polarizabilities and Rydberg states of open shell atomic systems View Full Text


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Article Info

DATE

1988-12

AUTHORS

P. K. Mukherjee, K. Ohtsuki, K. Ohno

ABSTRACT

Time dependent coupled Hartree-Fock (TDCHF) theory is applied to calculate frequency dependent polarizabilities, transition energies, oscillator strengths and effective quantum numbers of several excited states of the open shell ions Al, Si+, P2+, S3+, Cl4+, Ar5+, Cl and Ar+ in the 2P state within and beyond the normal dispersion region. The Roothaan formalism has been adopted to deal with the open shell problem. The excitation energies are extracted from the positions of the poles of an appropriate functional. Analytic representations of the singly excited Rydberg states have been found. The results obtained compare well with spectroscopic and other elaborate theoretical data wherever available. Inner shell excitations have been found for the first time within TDCHF theory. More... »

PAGES

431-444

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00528015

DOI

http://dx.doi.org/10.1007/bf00528015

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009510516


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