Etude théorique du pK des états excités View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1969-01

AUTHORS

J. Bertrán, O. Chalvet, R. Daudel

ABSTRACT

On montre à partir de considérations théoriques qu'une molécule conjugée dont un substituant donneur d'électrons est le centre d'acidité doit devenir plus acide quand eile passe de l'état fondamental au premier état électronique excité. Le contraire doit se produire lorsque le substituant est accepteur d'électrons. Enfin une molécule conjugée contenant un hétéroatome centre de basicité doit devenir plus basique au cours de la mÊme transition. On suggère, par ailleurs, une interprétation du fait que dans cette série de molécules le premier état excité triplet possède une force acido-basique très differente de celle du premier état excité singlet. More... »

PAGES

1-16

Journal

TITLE

Theoretical Chemistry Accounts

ISSUE

1

VOLUME

14

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00527323

DOI

http://dx.doi.org/10.1007/bf00527323

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1035825518


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