Effect of the size of the aliphatic chain on the NMR spectra and the electrical conductivity of melts of alkali ... View Full Text


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Article Info

DATE

1994-01

AUTHORS

T. A. Mirnaya, V. V. Trachevskii, S. V. Volkov, Yu. V. Bereznitsxmkii

ABSTRACT

The dependence of NMR spectra of 7Li, 23Na, 133Cs and of the conductivity of melts of lithium, sodium, and cesium alkanoates in melts of alkanoic acids on the length of the aliphatic chain of the anion has been studied. As the anion size increases, chemical shifts of 23Na and 133Cs nuclei toward weak fields and 7Li nuclei toward strong fields are observed. The nature of the chemical shifts of alkali metal nuclei and of the electricity transport characteristic in the studied systems is discussed in connection with the nature of cation-anion interactions and the size and degree of free rotation of the anion. More... »

PAGES

59-62

References to SciGraph publications

  • 1976-10. Investigation of the thermal behaviour of fatty acid sodium salts in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
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    http://scigraph.springernature.com/pub.10.1007/bf00520264

    DOI

    http://dx.doi.org/10.1007/bf00520264

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