Reactions of azirines with sulfur nucleophiles. 4. Treatment of 2H-azirine with mercaptosubstituted acids. reactions of aziridinyl alkyl sulfides with carboxylic ... View Full Text


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Article Info

DATE

1986-02

AUTHORS

R. S. Él'kinson, A. V. Eremeev

ABSTRACT

Treatment of 2H-azirines with mercaptosubstituted acids and their derivatives leads to β-ketoamides and 2-aziridinyl alkyl sulfides, respectively. 2-Aziridinyl alkyl sulfides, in turn, react with carboxylic acids to give β-ketoamides and substituted ethanethiol derivatives. Acylation of 2-aziridinyl alkyl sulfides with acyl halides generates a variety of products, depending on the reaction conditions; either products derived from cleavage and isomerization of the aziridinyl ring or (1-acylaziridinyl-2) alkyl sulfides are obtained. More... »

PAGES

161-166

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00519936

DOI

http://dx.doi.org/10.1007/bf00519936

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030556772


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