Synthesis and absolute configurations of diastereomeric aziridine-2-carboxylic acid derivatives containing valine and hexafluorovaline fragments View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1985-10

AUTHORS

I. V. Solodin, F. D. Polyak, A. V. Eremeev, I. A. Vosekalna, É. É. Liepin'sh, I. I. Chervin, R. G. Kostyanovskii

ABSTRACT

Individual diastereomers of aziridine-2-carboxylic acid esters that contain R- and S-valine and R- and S-hexafluorovaline fragments were isolated by high-performance liquid chromatogrpahy (HPLC). The absolute configurations of both asymmetric centers of the diastereomeric esters were determined on the basis of the parameters of the PMR spectra (ΔυAB) and circular dichroism (the sign of the cotton effect at 200–220 nm). More... »

PAGES

1110-1113

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00515248

DOI

http://dx.doi.org/10.1007/bf00515248

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005952284


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