Synthesis of derivatives of tetrahydrofuran and tetrahydropyran by intramolecular cyclization of unsaturated hydroxy compounds (review) View Full Text


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Article Info

DATE

1982-11

AUTHORS

Yu. I. Gevaza, V. I. Staninets

ABSTRACT

The literature data on reactions involving electrophilic heterocyclization of δ, ɛ-unsaturated alcohols, 2-allylphenols, oxiranes, aldehydes, and ketones are correlated. The factors that affects the reactivities of the unsaturated compounds (the structure of the substrate, the nature of the electrophile, and the nature of the solvent) in intramolecular cyclization are discussed. The problems of the regioselectivity of the addition and the stereochemistry of the resulting cyclization products are examined, and kinetic data are presented. More... »

PAGES

1115-1132

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00506356

DOI

http://dx.doi.org/10.1007/bf00506356

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041991270


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