Dependence of the reactivity of five-membered aromatic heterocycles on their structure. 1. Effect of the number, type, and position of ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1987-01

AUTHORS

V. G. Andrianov, M. A. Shokhen, A. V. Eremeev, S. V. Barmina

ABSTRACT

The proton affinities (PA) of 16 aminoazoles were calculated by the MNDO and ab initio methods. It was assumed that the effect of the heteroatom on the PA is determined by its type and position and does not depend on the presence of other heteroatoms in the ring. Quantitative characteristics reflecting the effect of heteroatoms at various positions on the PA were obtained by the method of least squares. More... »

PAGES

44-48

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00475472

DOI

http://dx.doi.org/10.1007/bf00475472

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016590552


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga", 
          "id": "http://www.grid.ac/institutes/grid.419212.d", 
          "name": [
            "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Andrianov", 
        "givenName": "V. G.", 
        "id": "sg:person.016164060371.30", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016164060371.30"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga", 
          "id": "http://www.grid.ac/institutes/grid.419212.d", 
          "name": [
            "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shokhen", 
        "givenName": "M. A.", 
        "id": "sg:person.0635040367.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0635040367.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga", 
          "id": "http://www.grid.ac/institutes/grid.419212.d", 
          "name": [
            "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Eremeev", 
        "givenName": "A. V.", 
        "id": "sg:person.014471236413.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014471236413.16"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga", 
          "id": "http://www.grid.ac/institutes/grid.419212.d", 
          "name": [
            "Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Barmina", 
        "givenName": "S. V.", 
        "id": "sg:person.07473163733.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07473163733.42"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1987-01", 
    "datePublishedReg": "1987-01-01", 
    "description": "The proton affinities (PA) of 16 aminoazoles were calculated by the MNDO and ab initio methods. It was assumed that the effect of the heteroatom on the PA is determined by its type and position and does not depend on the presence of other heteroatoms in the ring. Quantitative characteristics reflecting the effect of heteroatoms at various positions on the PA were obtained by the method of least squares.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf00475472", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1429545", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "23"
      }
    ], 
    "keywords": [
      "least squares", 
      "ab initio methods", 
      "quantitative characteristics", 
      "initio methods", 
      "squares", 
      "effect of heteroatoms", 
      "dependence", 
      "atoms", 
      "position", 
      "MNDO", 
      "nitrogen atoms", 
      "structure", 
      "number", 
      "types", 
      "effect", 
      "ring", 
      "characteristics", 
      "presence", 
      "heteroatoms", 
      "proton affinity", 
      "aminoazoles", 
      "aromatic heterocycles", 
      "affinity", 
      "heterocycles", 
      "reactivity", 
      "method"
    ], 
    "name": "Dependence of the reactivity of five-membered aromatic heterocycles on their structure. 1. Effect of the number, type, and position of nitrogen atoms on the proton affinity of aminoazoles", 
    "pagination": "44-48", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1016590552"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00475472"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00475472", 
      "https://app.dimensions.ai/details/publication/pub.1016590552"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-12-01T06:19", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_207.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf00475472"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00475472'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00475472'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00475472'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00475472'


 

This table displays all metadata directly associated to this object as RDF triples.

104 TRIPLES      20 PREDICATES      51 URIs      43 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00475472 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Ncef49d100a8a4cf4aa88c68ef9578449
4 schema:datePublished 1987-01
5 schema:datePublishedReg 1987-01-01
6 schema:description The proton affinities (PA) of 16 aminoazoles were calculated by the MNDO and ab initio methods. It was assumed that the effect of the heteroatom on the PA is determined by its type and position and does not depend on the presence of other heteroatoms in the ring. Quantitative characteristics reflecting the effect of heteroatoms at various positions on the PA were obtained by the method of least squares.
7 schema:genre article
8 schema:isAccessibleForFree false
9 schema:isPartOf N0e23cd9ed6064707887d51926c4d379f
10 N7dd00725a8504002a44ea1f7c057c342
11 sg:journal.1429545
12 schema:keywords MNDO
13 ab initio methods
14 affinity
15 aminoazoles
16 aromatic heterocycles
17 atoms
18 characteristics
19 dependence
20 effect
21 effect of heteroatoms
22 heteroatoms
23 heterocycles
24 initio methods
25 least squares
26 method
27 nitrogen atoms
28 number
29 position
30 presence
31 proton affinity
32 quantitative characteristics
33 reactivity
34 ring
35 squares
36 structure
37 types
38 schema:name Dependence of the reactivity of five-membered aromatic heterocycles on their structure. 1. Effect of the number, type, and position of nitrogen atoms on the proton affinity of aminoazoles
39 schema:pagination 44-48
40 schema:productId N2cdfe92f8cea4ad9b966164386146437
41 N3fcb7f29c7b24d959895eca33b39e1aa
42 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016590552
43 https://doi.org/10.1007/bf00475472
44 schema:sdDatePublished 2022-12-01T06:19
45 schema:sdLicense https://scigraph.springernature.com/explorer/license/
46 schema:sdPublisher Nbf0a34fa05db41ea95b415f5a384a67d
47 schema:url https://doi.org/10.1007/bf00475472
48 sgo:license sg:explorer/license/
49 sgo:sdDataset articles
50 rdf:type schema:ScholarlyArticle
51 N0e23cd9ed6064707887d51926c4d379f schema:volumeNumber 23
52 rdf:type schema:PublicationVolume
53 N2cdfe92f8cea4ad9b966164386146437 schema:name doi
54 schema:value 10.1007/bf00475472
55 rdf:type schema:PropertyValue
56 N3fcb7f29c7b24d959895eca33b39e1aa schema:name dimensions_id
57 schema:value pub.1016590552
58 rdf:type schema:PropertyValue
59 N54b421ce39154c2dbb9ada25047311b7 rdf:first sg:person.07473163733.42
60 rdf:rest rdf:nil
61 N619945ac9bf341aeae4671e071f3d720 rdf:first sg:person.014471236413.16
62 rdf:rest N54b421ce39154c2dbb9ada25047311b7
63 N7dd00725a8504002a44ea1f7c057c342 schema:issueNumber 1
64 rdf:type schema:PublicationIssue
65 Na4bdd8924b62463eb2aee559156d664f rdf:first sg:person.0635040367.70
66 rdf:rest N619945ac9bf341aeae4671e071f3d720
67 Nbf0a34fa05db41ea95b415f5a384a67d schema:name Springer Nature - SN SciGraph project
68 rdf:type schema:Organization
69 Ncef49d100a8a4cf4aa88c68ef9578449 rdf:first sg:person.016164060371.30
70 rdf:rest Na4bdd8924b62463eb2aee559156d664f
71 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
72 schema:name Chemical Sciences
73 rdf:type schema:DefinedTerm
74 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
75 schema:name Physical Chemistry (incl. Structural)
76 rdf:type schema:DefinedTerm
77 sg:journal.1429545 schema:issn 0132-6244
78 1573-8353
79 schema:name Chemistry of Heterocyclic Compounds
80 schema:publisher Springer Nature
81 rdf:type schema:Periodical
82 sg:person.014471236413.16 schema:affiliation grid-institutes:grid.419212.d
83 schema:familyName Eremeev
84 schema:givenName A. V.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014471236413.16
86 rdf:type schema:Person
87 sg:person.016164060371.30 schema:affiliation grid-institutes:grid.419212.d
88 schema:familyName Andrianov
89 schema:givenName V. G.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016164060371.30
91 rdf:type schema:Person
92 sg:person.0635040367.70 schema:affiliation grid-institutes:grid.419212.d
93 schema:familyName Shokhen
94 schema:givenName M. A.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0635040367.70
96 rdf:type schema:Person
97 sg:person.07473163733.42 schema:affiliation grid-institutes:grid.419212.d
98 schema:familyName Barmina
99 schema:givenName S. V.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07473163733.42
101 rdf:type schema:Person
102 grid-institutes:grid.419212.d schema:alternateName Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga
103 schema:name Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga
104 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...