Rearrangements of 1-oxa-2-azoles. 3. Rearrangement of 1,2,4-oxadiazole-3-carboxylic acid amidoximes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1991-06

AUTHORS

V. G. Andrianov, V. G. Semenikhina, A. V. Eremeev

ABSTRACT

The rearrangement of unsubstituted 1,2,4-oxadiazole-3-carboxylic acid amidoxime and its N-isopropyl derivative to an aminofurazan is catalyzed by ammonia, while in the case of the amidoxime containing a piperidino substituent the rearrangement is catalyzed by acids. In ammonium hydroxide the piperidino and imidazolyl derivatives are converted to cyano amidoximes as a result of opening of the oxadiazole ring. More... »

PAGES

646-650

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00472517

DOI

http://dx.doi.org/10.1007/bf00472517

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031294899


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis, Latvian Academy of Sciences, 226006, Riga", 
          "id": "http://www.grid.ac/institutes/grid.419207.9", 
          "name": [
            "Institute of Organic Synthesis, Latvian Academy of Sciences, 226006, Riga"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Andrianov", 
        "givenName": "V. G.", 
        "id": "sg:person.016164060371.30", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016164060371.30"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis, Latvian Academy of Sciences, 226006, Riga", 
          "id": "http://www.grid.ac/institutes/grid.419207.9", 
          "name": [
            "Institute of Organic Synthesis, Latvian Academy of Sciences, 226006, Riga"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Semenikhina", 
        "givenName": "V. G.", 
        "id": "sg:person.07461007171.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07461007171.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis, Latvian Academy of Sciences, 226006, Riga", 
          "id": "http://www.grid.ac/institutes/grid.419207.9", 
          "name": [
            "Institute of Organic Synthesis, Latvian Academy of Sciences, 226006, Riga"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Eremeev", 
        "givenName": "A. V.", 
        "id": "sg:person.014471236413.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014471236413.16"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1991-06", 
    "datePublishedReg": "1991-06-01", 
    "description": "The rearrangement of unsubstituted 1,2,4-oxadiazole-3-carboxylic acid amidoxime and its N-isopropyl derivative to an aminofurazan is catalyzed by ammonia, while in the case of the amidoxime containing a piperidino substituent the rearrangement is catalyzed by acids. In ammonium hydroxide the piperidino and imidazolyl derivatives are converted to cyano amidoximes as a result of opening of the oxadiazole ring.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf00472517", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1429545", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "27"
      }
    ], 
    "keywords": [
      "cases", 
      "piperidino substituent", 
      "rearrangement", 
      "imidazolyl derivatives", 
      "isopropyl derivatives", 
      "acid", 
      "result of opening", 
      "derivatives", 
      "results", 
      "opening", 
      "oxadiazole ring", 
      "amidoximes", 
      "aminofurazans", 
      "ring", 
      "ammonia", 
      "substituents", 
      "ammonium hydroxide", 
      "hydroxide"
    ], 
    "name": "Rearrangements of 1-oxa-2-azoles. 3. Rearrangement of 1,2,4-oxadiazole-3-carboxylic acid amidoximes", 
    "pagination": "646-650", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1031294899"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00472517"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00472517", 
      "https://app.dimensions.ai/details/publication/pub.1031294899"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-12-01T06:19", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_218.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf00472517"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00472517'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00472517'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00472517'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00472517'


 

This table displays all metadata directly associated to this object as RDF triples.

89 TRIPLES      20 PREDICATES      43 URIs      35 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00472517 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N2185e6ea69aa4657ba77fa438e80cc20
4 schema:datePublished 1991-06
5 schema:datePublishedReg 1991-06-01
6 schema:description The rearrangement of unsubstituted 1,2,4-oxadiazole-3-carboxylic acid amidoxime and its N-isopropyl derivative to an aminofurazan is catalyzed by ammonia, while in the case of the amidoxime containing a piperidino substituent the rearrangement is catalyzed by acids. In ammonium hydroxide the piperidino and imidazolyl derivatives are converted to cyano amidoximes as a result of opening of the oxadiazole ring.
7 schema:genre article
8 schema:isAccessibleForFree false
9 schema:isPartOf N18aa544610ca46889029b39f498b8f42
10 Nc08c9e913c214f4a998170b0e2ba2d91
11 sg:journal.1429545
12 schema:keywords acid
13 amidoximes
14 aminofurazans
15 ammonia
16 ammonium hydroxide
17 cases
18 derivatives
19 hydroxide
20 imidazolyl derivatives
21 isopropyl derivatives
22 opening
23 oxadiazole ring
24 piperidino substituent
25 rearrangement
26 result of opening
27 results
28 ring
29 substituents
30 schema:name Rearrangements of 1-oxa-2-azoles. 3. Rearrangement of 1,2,4-oxadiazole-3-carboxylic acid amidoximes
31 schema:pagination 646-650
32 schema:productId N8e8c5e0bab7d4fbdaf3ff1740bcdfa0f
33 Nd0547721f0a44b288267a1674279b4fe
34 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031294899
35 https://doi.org/10.1007/bf00472517
36 schema:sdDatePublished 2022-12-01T06:19
37 schema:sdLicense https://scigraph.springernature.com/explorer/license/
38 schema:sdPublisher Naed60238ab104be6a99c56bde448af89
39 schema:url https://doi.org/10.1007/bf00472517
40 sgo:license sg:explorer/license/
41 sgo:sdDataset articles
42 rdf:type schema:ScholarlyArticle
43 N18aa544610ca46889029b39f498b8f42 schema:volumeNumber 27
44 rdf:type schema:PublicationVolume
45 N2185e6ea69aa4657ba77fa438e80cc20 rdf:first sg:person.016164060371.30
46 rdf:rest Nfc3df421ab4841ccbfdd9df884a3bf6d
47 N50b03b9245d548c3997d80c67bd3cd1a rdf:first sg:person.014471236413.16
48 rdf:rest rdf:nil
49 N8e8c5e0bab7d4fbdaf3ff1740bcdfa0f schema:name doi
50 schema:value 10.1007/bf00472517
51 rdf:type schema:PropertyValue
52 Naed60238ab104be6a99c56bde448af89 schema:name Springer Nature - SN SciGraph project
53 rdf:type schema:Organization
54 Nc08c9e913c214f4a998170b0e2ba2d91 schema:issueNumber 6
55 rdf:type schema:PublicationIssue
56 Nd0547721f0a44b288267a1674279b4fe schema:name dimensions_id
57 schema:value pub.1031294899
58 rdf:type schema:PropertyValue
59 Nfc3df421ab4841ccbfdd9df884a3bf6d rdf:first sg:person.07461007171.11
60 rdf:rest N50b03b9245d548c3997d80c67bd3cd1a
61 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
62 schema:name Chemical Sciences
63 rdf:type schema:DefinedTerm
64 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
65 schema:name Physical Chemistry (incl. Structural)
66 rdf:type schema:DefinedTerm
67 sg:journal.1429545 schema:issn 0132-6244
68 1573-8353
69 schema:name Chemistry of Heterocyclic Compounds
70 schema:publisher Springer Nature
71 rdf:type schema:Periodical
72 sg:person.014471236413.16 schema:affiliation grid-institutes:grid.419207.9
73 schema:familyName Eremeev
74 schema:givenName A. V.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014471236413.16
76 rdf:type schema:Person
77 sg:person.016164060371.30 schema:affiliation grid-institutes:grid.419207.9
78 schema:familyName Andrianov
79 schema:givenName V. G.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016164060371.30
81 rdf:type schema:Person
82 sg:person.07461007171.11 schema:affiliation grid-institutes:grid.419207.9
83 schema:familyName Semenikhina
84 schema:givenName V. G.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07461007171.11
86 rdf:type schema:Person
87 grid-institutes:grid.419207.9 schema:alternateName Institute of Organic Synthesis, Latvian Academy of Sciences, 226006, Riga
88 schema:name Institute of Organic Synthesis, Latvian Academy of Sciences, 226006, Riga
89 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...