Synthesis of ethyl 2-alkylthio-2-oxazoline-5-carboxylate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1979-04

AUTHORS

O. N. Bubel', I. G. Tishchenko, O. A. Grinkevich

ABSTRACT

Glycidic esters react with excess alkyl thiocyanates in the presence of equimolar amounts of boron trifluoride etherate to give esters of 2-alkylthio-2-oxazoline-5-carboxylic acids. The structure of the products was confirmed by the data from the PMR and IR spectra.

PAGES

372-373

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00471765

DOI

http://dx.doi.org/10.1007/bf00471765

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1008593930


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "V. I. Lenin Belorussian State University, 220080, Minsk", 
          "id": "http://www.grid.ac/institutes/grid.17678.3f", 
          "name": [
            "V. I. Lenin Belorussian State University, 220080, Minsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bubel'", 
        "givenName": "O. N.", 
        "id": "sg:person.012765005437.97", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012765005437.97"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. I. Lenin Belorussian State University, 220080, Minsk", 
          "id": "http://www.grid.ac/institutes/grid.17678.3f", 
          "name": [
            "V. I. Lenin Belorussian State University, 220080, Minsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tishchenko", 
        "givenName": "I. G.", 
        "id": "sg:person.011152262415.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011152262415.47"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. I. Lenin Belorussian State University, 220080, Minsk", 
          "id": "http://www.grid.ac/institutes/grid.17678.3f", 
          "name": [
            "V. I. Lenin Belorussian State University, 220080, Minsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Grinkevich", 
        "givenName": "O. A.", 
        "id": "sg:person.014155414205.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014155414205.27"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1979-04", 
    "datePublishedReg": "1979-04-01", 
    "description": "Glycidic esters react with excess alkyl thiocyanates in the presence of equimolar amounts of boron trifluoride etherate to give esters of 2-alkylthio-2-oxazoline-5-carboxylic acids. The structure of the products was confirmed by the data from the PMR and IR spectra.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf00471765", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1429545", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "15"
      }
    ], 
    "keywords": [
      "boron trifluoride etherate", 
      "IR spectra", 
      "carboxylic acids", 
      "alkyl thiocyanates", 
      "trifluoride etherate", 
      "ethyl 2", 
      "equimolar amounts", 
      "glycidic esters", 
      "esters", 
      "carboxylate", 
      "etherate", 
      "thiocyanate", 
      "synthesis", 
      "acid", 
      "PMR", 
      "spectra", 
      "structure", 
      "products", 
      "presence", 
      "amount", 
      "data"
    ], 
    "name": "Synthesis of ethyl 2-alkylthio-2-oxazoline-5-carboxylate", 
    "pagination": "372-373", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1008593930"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00471765"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00471765", 
      "https://app.dimensions.ai/details/publication/pub.1008593930"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-10T09:39", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220509/entities/gbq_results/article/article_146.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf00471765"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00471765'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00471765'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00471765'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00471765'


 

This table displays all metadata directly associated to this object as RDF triples.

93 TRIPLES      21 PREDICATES      47 URIs      39 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00471765 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N276ff15bf1574d28a026e5c28f11a8a9
4 schema:datePublished 1979-04
5 schema:datePublishedReg 1979-04-01
6 schema:description Glycidic esters react with excess alkyl thiocyanates in the presence of equimolar amounts of boron trifluoride etherate to give esters of 2-alkylthio-2-oxazoline-5-carboxylic acids. The structure of the products was confirmed by the data from the PMR and IR spectra.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N06e8b1108a154a17aa6064413ef4af6b
11 Na5f57aaf30b3431393846b2ebf77e8af
12 sg:journal.1429545
13 schema:keywords IR spectra
14 PMR
15 acid
16 alkyl thiocyanates
17 amount
18 boron trifluoride etherate
19 carboxylate
20 carboxylic acids
21 data
22 equimolar amounts
23 esters
24 etherate
25 ethyl 2
26 glycidic esters
27 presence
28 products
29 spectra
30 structure
31 synthesis
32 thiocyanate
33 trifluoride etherate
34 schema:name Synthesis of ethyl 2-alkylthio-2-oxazoline-5-carboxylate
35 schema:pagination 372-373
36 schema:productId N0dc98418b9c34093ad0866e4d9965cf3
37 Ncfa527da563a4f799041a988c8f260b3
38 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008593930
39 https://doi.org/10.1007/bf00471765
40 schema:sdDatePublished 2022-05-10T09:39
41 schema:sdLicense https://scigraph.springernature.com/explorer/license/
42 schema:sdPublisher N1a997d084fb54b23bdfb0c041e28ae63
43 schema:url https://doi.org/10.1007/bf00471765
44 sgo:license sg:explorer/license/
45 sgo:sdDataset articles
46 rdf:type schema:ScholarlyArticle
47 N06e8b1108a154a17aa6064413ef4af6b schema:volumeNumber 15
48 rdf:type schema:PublicationVolume
49 N0dc98418b9c34093ad0866e4d9965cf3 schema:name dimensions_id
50 schema:value pub.1008593930
51 rdf:type schema:PropertyValue
52 N1a997d084fb54b23bdfb0c041e28ae63 schema:name Springer Nature - SN SciGraph project
53 rdf:type schema:Organization
54 N276ff15bf1574d28a026e5c28f11a8a9 rdf:first sg:person.012765005437.97
55 rdf:rest N31ef5128886f4965a8937c721f262916
56 N31ef5128886f4965a8937c721f262916 rdf:first sg:person.011152262415.47
57 rdf:rest N875bf04c0f1f4bfc952505ccc0ce3144
58 N875bf04c0f1f4bfc952505ccc0ce3144 rdf:first sg:person.014155414205.27
59 rdf:rest rdf:nil
60 Na5f57aaf30b3431393846b2ebf77e8af schema:issueNumber 4
61 rdf:type schema:PublicationIssue
62 Ncfa527da563a4f799041a988c8f260b3 schema:name doi
63 schema:value 10.1007/bf00471765
64 rdf:type schema:PropertyValue
65 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
66 schema:name Chemical Sciences
67 rdf:type schema:DefinedTerm
68 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
69 schema:name Organic Chemistry
70 rdf:type schema:DefinedTerm
71 sg:journal.1429545 schema:issn 0132-6244
72 1573-8353
73 schema:name Chemistry of Heterocyclic Compounds
74 schema:publisher Springer Nature
75 rdf:type schema:Periodical
76 sg:person.011152262415.47 schema:affiliation grid-institutes:grid.17678.3f
77 schema:familyName Tishchenko
78 schema:givenName I. G.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011152262415.47
80 rdf:type schema:Person
81 sg:person.012765005437.97 schema:affiliation grid-institutes:grid.17678.3f
82 schema:familyName Bubel'
83 schema:givenName O. N.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012765005437.97
85 rdf:type schema:Person
86 sg:person.014155414205.27 schema:affiliation grid-institutes:grid.17678.3f
87 schema:familyName Grinkevich
88 schema:givenName O. A.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014155414205.27
90 rdf:type schema:Person
91 grid-institutes:grid.17678.3f schema:alternateName V. I. Lenin Belorussian State University, 220080, Minsk
92 schema:name V. I. Lenin Belorussian State University, 220080, Minsk
93 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...