Ontology type: schema:ScholarlyArticle
1973-08
AUTHORSV. M. Cherkasov, L. P. Prikazchikova, B. M. Chutova, I. F. Vladimirtsev, I. V. Boldyrev
ABSTRACTThe reaction of methyl groups with acyl chlorides is described for the first time in the pyrimidine series. The corresponding ketones — 6-methyl-4-phenacylpyrimidines — have been obtained from 4,6-dimethylpyrimidine and chlorides or aromatic carboxylic acids. A possible mechanism of the reaction is discussed.
PAGES1045-1047
http://scigraph.springernature.com/pub.10.1007/bf00471728
DOIhttp://dx.doi.org/10.1007/bf00471728
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1004327426
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Organic Chemistry",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev",
"id": "http://www.grid.ac/institutes/grid.464621.3",
"name": [
"Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev"
],
"type": "Organization"
},
"familyName": "Cherkasov",
"givenName": "V. M.",
"id": "sg:person.010623734217.24",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010623734217.24"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev",
"id": "http://www.grid.ac/institutes/grid.464621.3",
"name": [
"Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev"
],
"type": "Organization"
},
"familyName": "Prikazchikova",
"givenName": "L. P.",
"id": "sg:person.011154717107.95",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011154717107.95"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev",
"id": "http://www.grid.ac/institutes/grid.464621.3",
"name": [
"Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev"
],
"type": "Organization"
},
"familyName": "Chutova",
"givenName": "B. M.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev",
"id": "http://www.grid.ac/institutes/grid.464621.3",
"name": [
"Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev"
],
"type": "Organization"
},
"familyName": "Vladimirtsev",
"givenName": "I. F.",
"id": "sg:person.015204577217.24",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015204577217.24"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev",
"id": "http://www.grid.ac/institutes/grid.464621.3",
"name": [
"Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev"
],
"type": "Organization"
},
"familyName": "Boldyrev",
"givenName": "I. V.",
"id": "sg:person.011534222675.16",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011534222675.16"
],
"type": "Person"
}
],
"datePublished": "1973-08",
"datePublishedReg": "1973-08-01",
"description": "The reaction of methyl groups with acyl chlorides is described for the first time in the pyrimidine series. The corresponding ketones \u2014 6-methyl-4-phenacylpyrimidines \u2014 have been obtained from 4,6-dimethylpyrimidine and chlorides or aromatic carboxylic acids. A possible mechanism of the reaction is discussed.",
"genre": "article",
"id": "sg:pub.10.1007/bf00471728",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1429545",
"issn": [
"0132-6244",
"1573-8353"
],
"name": "Chemistry of Heterocyclic Compounds",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "8",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "9"
}
],
"keywords": [
"possible mechanism",
"group",
"acid",
"first time",
"mechanism",
"reaction",
"chloride",
"time",
"pyrimidine series",
"series",
"carboxylic acids",
"methyl group",
"dimethylpyrimidine",
"aromatic carboxylic acids",
"acyl chlorides"
],
"name": "Reaction of 4,6-dimethylpyrimidine with chlorides of aromatic carboxylic acids",
"pagination": "1045-1047",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1004327426"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf00471728"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf00471728",
"https://app.dimensions.ai/details/publication/pub.1004327426"
],
"sdDataset": "articles",
"sdDatePublished": "2022-05-20T07:17",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_150.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/bf00471728"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00471728'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00471728'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00471728'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00471728'
This table displays all metadata directly associated to this object as RDF triples.
100 TRIPLES
21 PREDICATES
41 URIs
33 LITERALS
6 BLANK NODES