Ferric-ferrous equilibria in natural silicate liquids at 1 bar View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1981-02

AUTHORS

R. O. Sack, I. S. E. Carmichael, M. Rivers, M. S. Ghiorso

ABSTRACT

Ferric and ferrous iron concentrations have been measured in 57 silicate liquids equilibrated at temperatures (1,200°–1,330°C) above the liquidus and at oxygen fugacities close to those defined by quartz-fayalite-magnetite. The experimental results reported here span virtually the entire known compositional range of lavas. An empirical equation relating the mole fraction of Fe2O3 and FeO to oxygen fugacity, absolute temperature and liquid composition at 1 bar has been formulated, based on the present experimental results and published data. Extrapolating the proposed empirical relationship over several hundred degrees, for instance below the solidus of the 1965 Makaopuhi tholeiitic lava lake, yields calculated oxygen fugacities which are a little lower than those measured directly in drill holes; at 1,100°C this discrepancy is 0.4 log unit. However, the agreement between the oxygen fugacities calculated from our empirical equation and those indicated by the composition of Fe-Ti oxides in andesites and siliceous obsidians is much closer. More... »

PAGES

369-376

References to SciGraph publications

  • 1980-03. A regular solution model for met-aluminous silicate liquids: Applications to geothermometry, immiscibility, and the source regions of basic magmas in CONTRIBUTIONS TO MINERALOGY AND PETROLOGY
  • 1971-03. Silica activity and Ptotal in igneous rocks in CONTRIBUTIONS TO MINERALOGY AND PETROLOGY
  • 1982-10. The Colima volcanic complex, Mexico:III in CONTRIBUTIONS TO MINERALOGY AND PETROLOGY
  • 1979-09. Abyssal tholeiites from the Oceanographer Fracture Zone in CONTRIBUTIONS TO MINERALOGY AND PETROLOGY
  • 1977. Thermodynamic Properties of Silicate Melts in THERMODYNAMICS IN GEOLOGY
  • 1966-03. The iron-titanium oxides of salic volcanic rocks and their associated ferromagnesian silicates in CONTRIBUTIONS TO MINERALOGY AND PETROLOGY
  • 1981-05. The Colima volcanic complex, Mexico: Part II. Late-quaternary cinder cones in CONTRIBUTIONS TO MINERALOGY AND PETROLOGY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf00374720

    DOI

    http://dx.doi.org/10.1007/bf00374720

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1051318819


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