Regularities of pyrolytic boron nitride coating formation on a graphite matrix View Full Text


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Article Info

DATE

1993-01

AUTHORS

A. S. Rozenberg, Yu. A. Sinenko, N. V. Chukanov

ABSTRACT

The kinetics and structure of chemical vapour-phase deposition of boron nitride ceramics on a graphite matrix from the mixture BCl3/NH3/N2 have been investigated for a wide range of conditions (temperature 1300–2100°C, pressure 130–2600 Pa, at varying partial pressures of the components). The growth-rate was found to vary non-linearly with the consumption rates of the reagents. The content of hexagonal components in the BN-ceramics rose, while the turbostrate microphase content diminished with temperature. The dependences of the concentrations of hexagonal, turbostratic and amorphous fractions in BN-ceramics on the reaction mixture composition and total pressure have been determined. More... »

PAGES

5528-5533

References to SciGraph publications

  • 1988-02. Density and deposition rate of chemical-vapour-deposited boron nitride in JOURNAL OF MATERIALS SCIENCE
  • 1986-02. Synthesis and structure of chemically vapour-deposited boron nitride in JOURNAL OF MATERIALS SCIENCE
  • 1981-08. Mechanism of formation of applicable linear boron-nitrogen polymers in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf00367825

    DOI

    http://dx.doi.org/10.1007/bf00367825

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1039435071


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