Toughened-hybrid epoxies: influence of the rubber-phase morphology on mechanical properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1994-01

AUTHORS

C. I. Vallo, Lijiang Hu, P. M. Frontini, R. J. J. Williams

ABSTRACT

A toughened-epoxy polymer based on diglycidylether of bisphenol A (DGEBA) cured with ethylenediamine (EDA) and modified with a rubber based on an epoxy-terminated acrylonitrile-butadiene random copolymer (ETBN), exhibited different morphologies depending on the rubber content. Up to 10% rubber, the morphology consisted of a random dispersion of spherical domains rich in rubber, while at 15% rubber, large and irregular domains were present, turning into a co-continuous structure at 20% rubber. Mechanical properties (elastic modulus, uniaxial compression yield stress, critical stress intensity factor, KIC and strain energy release rate, GIC) of the toughened epoxies and hybrid-particulate materials containing glass beads, were analysed. The best mechanical properties were exhibited by hybrids with a random dispersion of rubbery domains in the epoxy matrix. The presence of large and irregular domains or co-continuous structures led to materials with poor mechanical properties. More... »

PAGES

2481-2486

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00363443

DOI

http://dx.doi.org/10.1007/bf00363443

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052669314


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