Thin hydroxyapatite layers formed on porous titanium using electrochemical and hydrothermal reaction View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1996-01

AUTHORS

H. Ishizawa, M. Ogino

ABSTRACT

In our previous study, it was found that hydroxyapatite (HA) microcrystals were precipitated by hydrothermal treatment on an anodic titanium oxide film containing calcium and phosphorus (AOFCP) with an equivalent Ca/P ratio to HA, which was formed on a titanium metal anode in an aqueous electrolytic solution of dissolved calcium acetate and β-glycerophosphate. In this study, the formation mechanism of the AOFCP has been clarified. Spark discharges, which occur on titanium surface with a large amount of heat generation, cause crystallization of the TiO2 matrix of the AOFCP and incorporation of calcium and phosphorus into the matrix from these electrolytes simultaneously. The calcium and phosphorus in the matrix seem to exist as ions rather than as calcium phosphate. Also, thin HA layers consisting of the many precipitated microcrystals can be uniformly formed even on titanium with complex shapes or surface geometries such as the mesh, roughened surfaces and bead-coated porous coating by the present method. More... »

PAGES

6279-6284

References to SciGraph publications

  • 1992-11. Increasing of the corrosion resistance of the Ti6Al4V alloy by high thickness anodic oxidation in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN MEDICINE
  • 1991-01. Bioactive calcium phosphate coatings prepared by electrodeposition in JOURNAL OF MATERIALS SCIENCE LETTERS
  • 1995-02. Calcium phosphate coatings prepared by electrocrystallization from aqueous electrolytes in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN MEDICINE
  • Journal

    TITLE

    Journal of Materials Science

    ISSUE

    23

    VOLUME

    31

    Author Affiliations

    Related Patents

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf00354450

    DOI

    http://dx.doi.org/10.1007/bf00354450

    DIMENSIONS

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