A back-extraction procedure for the dithiocarbamate solvent extraction method. Rapid determination of metals in seawater matrices View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1992-01

AUTHORS

S. Sachsenberg, Th. Klenke, W. E. Krumbein, E. Zeeck

ABSTRACT

A ligand exchange liquid/liquid extraction method using dithiocarbamate complexes is elaborated for the graphite furnace atomic absorption spectrometry (GF-AAS) of seawater and marine interstitial water. Palladium is used for the exchange. This metal ensures a rapid and quantitative back-extraction. It simultaneously works as matrix modifier in the GF-AAS analysis. The proposed method is evaluated in the analysis of lead, copper, nickel, and cadmium in CASS-II marine reference seawater and samples from the North Sea. A microanalytical variant of the method is applied in marine interstitial water analysis down to sample volumes of 500 μl. More... »

PAGES

163-166

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00321714

DOI

http://dx.doi.org/10.1007/bf00321714

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1046696578


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