Ontology type: schema:ScholarlyArticle
1992-04
AUTHORSR. J. J. Williams, A. Vázquez, J. P. Pascault
ABSTRACTThe cyclotrimerization of dicyanates to form polycyanurate networks has been analyzed using a pure kinetic model and a combined kinetic-recursive procedure. In both cases substitution effects were considered, i.e. the reactivity of OCN groups pertainning to clusters was assumed lower than the corresponding reactivity of the monomer groups. The gel conversion varied from 1/2 (no substitutions effects) to 2/3 (infinite substitution effects). The evolution of trimer concentration along the reaction constitutes a direct experimental evidence to decide whether the polymerization follows or not an ideal course, described by the mean-field theory. More... »
PAGES219-225
http://scigraph.springernature.com/pub.10.1007/bf00299659
DOIhttp://dx.doi.org/10.1007/bf00299659
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