Gelation in the cyclotrimerization of dicyanates considering substitution effects View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1992-04

AUTHORS

R. J. J. Williams, A. Vázquez, J. P. Pascault

ABSTRACT

The cyclotrimerization of dicyanates to form polycyanurate networks has been analyzed using a pure kinetic model and a combined kinetic-recursive procedure. In both cases substitution effects were considered, i.e. the reactivity of OCN groups pertainning to clusters was assumed lower than the corresponding reactivity of the monomer groups. The gel conversion varied from 1/2 (no substitutions effects) to 2/3 (infinite substitution effects). The evolution of trimer concentration along the reaction constitutes a direct experimental evidence to decide whether the polymerization follows or not an ideal course, described by the mean-field theory. More... »

PAGES

219-225

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00299659

DOI

http://dx.doi.org/10.1007/bf00299659

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000252901


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0101", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Pure Mathematics", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/01", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Mathematical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Instituto de Investigaciones en Ciencia y Tecnolog\u00eda de Materiales", 
          "id": "https://www.grid.ac/institutes/grid.473319.b", 
          "name": [
            "Institute of Materials Science and Technology (INTEMA), University of Mar del Plata and National Research Council (CONICET), J.B. Justo 4302, (7600), Mar del Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Williams", 
        "givenName": "R. J. J.", 
        "id": "sg:person.013070001401.90", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013070001401.90"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Instituto de Investigaciones en Ciencia y Tecnolog\u00eda de Materiales", 
          "id": "https://www.grid.ac/institutes/grid.473319.b", 
          "name": [
            "Institute of Materials Science and Technology (INTEMA), University of Mar del Plata and National Research Council (CONICET), J.B. Justo 4302, (7600), Mar del Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "V\u00e1zquez", 
        "givenName": "A.", 
        "id": "sg:person.011104234531.74", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011104234531.74"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institut National des Sciences Appliqu\u00e9es de Lyon", 
          "id": "https://www.grid.ac/institutes/grid.15399.37", 
          "name": [
            "Laboratoire des Mat\u00e9riaux Macromol\u00e9culaires, URA CNRS no 507, Institut National des Sciences Appliqu\u00e9es de Lyon, 20 Av. A. Einstein, F-69621, Villeurbanne Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pascault", 
        "givenName": "J. P.", 
        "id": "sg:person.01154562041.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01154562041.52"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/masy.19910450114", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007552550"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/actp.1986.010371112", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010288408"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/masy.19910450113", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014398236"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/actp.1983.010341111", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025102551"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/masy.19890300103", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025991456"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pc.750080107", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030131735"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pc.750080107", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030131735"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/actp.1987.010380104", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046670682"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pol.1978.170160721", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052536753"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma00011a067", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056172870"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1992-04", 
    "datePublishedReg": "1992-04-01", 
    "description": "The cyclotrimerization of dicyanates to form polycyanurate networks has been analyzed using a pure kinetic model and a combined kinetic-recursive procedure. In both cases substitution effects were considered, i.e. the reactivity of OCN groups pertainning to clusters was assumed lower than the corresponding reactivity of the monomer groups. The gel conversion varied from 1/2 (no substitutions effects) to 2/3 (infinite substitution effects). The evolution of trimer concentration along the reaction constitutes a direct experimental evidence to decide whether the polymerization follows or not an ideal course, described by the mean-field theory.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00299659", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1123778", 
        "issn": [
          "0170-0839", 
          "1436-2449"
        ], 
        "name": "Polymer Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "28"
      }
    ], 
    "name": "Gelation in the cyclotrimerization of dicyanates considering substitution effects", 
    "pagination": "219-225", 
    "productId": [
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00299659"
        ]
      }, 
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "0133c5b5e59d6731403703c7d635d54ea1950219c31b693684029b83ab024090"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1000252901"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00299659", 
      "https://app.dimensions.ai/details/publication/pub.1000252901"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-15T08:54", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000374_0000000374/records_119752_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/BF00299659"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00299659'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00299659'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00299659'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00299659'


 

This table displays all metadata directly associated to this object as RDF triples.

105 TRIPLES      21 PREDICATES      36 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00299659 schema:about anzsrc-for:01
2 anzsrc-for:0101
3 schema:author Ne88d1cb6c0574bdfb29f2dcccb46c330
4 schema:citation https://doi.org/10.1002/actp.1983.010341111
5 https://doi.org/10.1002/actp.1986.010371112
6 https://doi.org/10.1002/actp.1987.010380104
7 https://doi.org/10.1002/masy.19890300103
8 https://doi.org/10.1002/masy.19910450113
9 https://doi.org/10.1002/masy.19910450114
10 https://doi.org/10.1002/pc.750080107
11 https://doi.org/10.1002/pol.1978.170160721
12 https://doi.org/10.1021/ma00011a067
13 schema:datePublished 1992-04
14 schema:datePublishedReg 1992-04-01
15 schema:description The cyclotrimerization of dicyanates to form polycyanurate networks has been analyzed using a pure kinetic model and a combined kinetic-recursive procedure. In both cases substitution effects were considered, i.e. the reactivity of OCN groups pertainning to clusters was assumed lower than the corresponding reactivity of the monomer groups. The gel conversion varied from 1/2 (no substitutions effects) to 2/3 (infinite substitution effects). The evolution of trimer concentration along the reaction constitutes a direct experimental evidence to decide whether the polymerization follows or not an ideal course, described by the mean-field theory.
16 schema:genre research_article
17 schema:inLanguage en
18 schema:isAccessibleForFree false
19 schema:isPartOf N7215687c804f41da91b3ee91bea0ced9
20 Nb2015f771cf34deb9318566823ef787b
21 sg:journal.1123778
22 schema:name Gelation in the cyclotrimerization of dicyanates considering substitution effects
23 schema:pagination 219-225
24 schema:productId N0c2afecdb355401f9be2ce7411b49b58
25 Na7fa30a1294243dc800aabcb8913d852
26 Nb540d90f85bb4531a182e81114c2e5f5
27 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000252901
28 https://doi.org/10.1007/bf00299659
29 schema:sdDatePublished 2019-04-15T08:54
30 schema:sdLicense https://scigraph.springernature.com/explorer/license/
31 schema:sdPublisher Nd410fc9df69c4509a33df22d87b847c5
32 schema:url http://link.springer.com/10.1007/BF00299659
33 sgo:license sg:explorer/license/
34 sgo:sdDataset articles
35 rdf:type schema:ScholarlyArticle
36 N0c2afecdb355401f9be2ce7411b49b58 schema:name doi
37 schema:value 10.1007/bf00299659
38 rdf:type schema:PropertyValue
39 N7215687c804f41da91b3ee91bea0ced9 schema:volumeNumber 28
40 rdf:type schema:PublicationVolume
41 Na34db65165ed48e9ae31846a0299fafc rdf:first sg:person.01154562041.52
42 rdf:rest rdf:nil
43 Na7fa30a1294243dc800aabcb8913d852 schema:name readcube_id
44 schema:value 0133c5b5e59d6731403703c7d635d54ea1950219c31b693684029b83ab024090
45 rdf:type schema:PropertyValue
46 Nb2015f771cf34deb9318566823ef787b schema:issueNumber 2
47 rdf:type schema:PublicationIssue
48 Nb540d90f85bb4531a182e81114c2e5f5 schema:name dimensions_id
49 schema:value pub.1000252901
50 rdf:type schema:PropertyValue
51 Nd410fc9df69c4509a33df22d87b847c5 schema:name Springer Nature - SN SciGraph project
52 rdf:type schema:Organization
53 Nd66f64ff42364362836a1bf711abf7ba rdf:first sg:person.011104234531.74
54 rdf:rest Na34db65165ed48e9ae31846a0299fafc
55 Ne88d1cb6c0574bdfb29f2dcccb46c330 rdf:first sg:person.013070001401.90
56 rdf:rest Nd66f64ff42364362836a1bf711abf7ba
57 anzsrc-for:01 schema:inDefinedTermSet anzsrc-for:
58 schema:name Mathematical Sciences
59 rdf:type schema:DefinedTerm
60 anzsrc-for:0101 schema:inDefinedTermSet anzsrc-for:
61 schema:name Pure Mathematics
62 rdf:type schema:DefinedTerm
63 sg:journal.1123778 schema:issn 0170-0839
64 1436-2449
65 schema:name Polymer Bulletin
66 rdf:type schema:Periodical
67 sg:person.011104234531.74 schema:affiliation https://www.grid.ac/institutes/grid.473319.b
68 schema:familyName Vázquez
69 schema:givenName A.
70 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011104234531.74
71 rdf:type schema:Person
72 sg:person.01154562041.52 schema:affiliation https://www.grid.ac/institutes/grid.15399.37
73 schema:familyName Pascault
74 schema:givenName J. P.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01154562041.52
76 rdf:type schema:Person
77 sg:person.013070001401.90 schema:affiliation https://www.grid.ac/institutes/grid.473319.b
78 schema:familyName Williams
79 schema:givenName R. J. J.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013070001401.90
81 rdf:type schema:Person
82 https://doi.org/10.1002/actp.1983.010341111 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025102551
83 rdf:type schema:CreativeWork
84 https://doi.org/10.1002/actp.1986.010371112 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010288408
85 rdf:type schema:CreativeWork
86 https://doi.org/10.1002/actp.1987.010380104 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046670682
87 rdf:type schema:CreativeWork
88 https://doi.org/10.1002/masy.19890300103 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025991456
89 rdf:type schema:CreativeWork
90 https://doi.org/10.1002/masy.19910450113 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014398236
91 rdf:type schema:CreativeWork
92 https://doi.org/10.1002/masy.19910450114 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007552550
93 rdf:type schema:CreativeWork
94 https://doi.org/10.1002/pc.750080107 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030131735
95 rdf:type schema:CreativeWork
96 https://doi.org/10.1002/pol.1978.170160721 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052536753
97 rdf:type schema:CreativeWork
98 https://doi.org/10.1021/ma00011a067 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056172870
99 rdf:type schema:CreativeWork
100 https://www.grid.ac/institutes/grid.15399.37 schema:alternateName Institut National des Sciences Appliquées de Lyon
101 schema:name Laboratoire des Matériaux Macromoléculaires, URA CNRS no 507, Institut National des Sciences Appliquées de Lyon, 20 Av. A. Einstein, F-69621, Villeurbanne Cedex, France
102 rdf:type schema:Organization
103 https://www.grid.ac/institutes/grid.473319.b schema:alternateName Instituto de Investigaciones en Ciencia y Tecnología de Materiales
104 schema:name Institute of Materials Science and Technology (INTEMA), University of Mar del Plata and National Research Council (CONICET), J.B. Justo 4302, (7600), Mar del Plata, Argentina
105 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...