Formation of poly(urethane-isocyanurate) networks from poly(oxypropylene)diols and diisocyanate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-07

AUTHORS

M. Špírková, J. Budinski-Simendic, M. Ilavský, P. Špaček, K. Dušek

ABSTRACT

Reaction conditions leading to the smallest amount of unreacted isocyanate groups for the preparation of poly(urethane-isocyanurate) networks based on 2,4-tolylene diisocyanate and α,ω-dihydroxypoly(oxypropylene) (Mn = 425−) were found. A tertiary amine, POLYCAT* 41, was used as a cyclotrimerization catalyst. The networks were prepared by prepolymer two-stage technique. The content of isocyanate groups in the prepolymers and networks was determined by potentiometric titration. Model reactions in 1,4-dioxane were used for the estimation of possible reaction intermediates during poly(urethane-isocyanurate) synthesis. More... »

PAGES

83-88

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00298768

DOI

http://dx.doi.org/10.1007/bf00298768

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040348481


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Macromolecular Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.424999.b", 
          "name": [
            "Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06, Prague 6, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "\u0160p\u00edrkov\u00e1", 
        "givenName": "M.", 
        "id": "sg:person.011363663463.39", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011363663463.39"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Novi Sad", 
          "id": "https://www.grid.ac/institutes/grid.10822.39", 
          "name": [
            "Faculty of Technology, University of Novi Sad, Novi Sad, Yugoslavia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Budinski-Simendic", 
        "givenName": "J.", 
        "id": "sg:person.011376060235.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011376060235.02"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Macromolecular Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.424999.b", 
          "name": [
            "Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06, Prague 6, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ilavsk\u00fd", 
        "givenName": "M.", 
        "id": "sg:person.013710523716.57", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013710523716.57"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Macromolecular Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.424999.b", 
          "name": [
            "Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06, Prague 6, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "\u0160pa\u010dek", 
        "givenName": "P.", 
        "id": "sg:person.016154462031.90", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016154462031.90"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Macromolecular Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.424999.b", 
          "name": [
            "Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06, Prague 6, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Du\u0161ek", 
        "givenName": "K.", 
        "id": "sg:person.01151570140.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01151570140.64"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/apmc.1990.051790107", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001194899"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(83)90148-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002937764"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(83)90148-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002937764"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00222338708076935", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003965156"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00255211", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039532314", 
          "https://doi.org/10.1007/bf00255211"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00255211", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039532314", 
          "https://doi.org/10.1007/bf00255211"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1993-07", 
    "datePublishedReg": "1993-07-01", 
    "description": "Reaction conditions leading to the smallest amount of unreacted isocyanate groups for the preparation of poly(urethane-isocyanurate) networks based on 2,4-tolylene diisocyanate and \u03b1,\u03c9-dihydroxypoly(oxypropylene) (Mn = 425\u2212) were found. A tertiary amine, POLYCAT* 41, was used as a cyclotrimerization catalyst. The networks were prepared by prepolymer two-stage technique. The content of isocyanate groups in the prepolymers and networks was determined by potentiometric titration. Model reactions in 1,4-dioxane were used for the estimation of possible reaction intermediates during poly(urethane-isocyanurate) synthesis.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00298768", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1123778", 
        "issn": [
          "0170-0839", 
          "1436-2449"
        ], 
        "name": "Polymer Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "31"
      }
    ], 
    "name": "Formation of poly(urethane-isocyanurate) networks from poly(oxypropylene)diols and diisocyanate", 
    "pagination": "83-88", 
    "productId": [
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00298768"
        ]
      }, 
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "c033c8d46998c671765318bb8e0ba28521f14d35257e483d314ddb919fd0316b"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1040348481"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00298768", 
      "https://app.dimensions.ai/details/publication/pub.1040348481"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-15T08:54", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000374_0000000374/records_119754_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/BF00298768"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00298768'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00298768'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00298768'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00298768'


 

This table displays all metadata directly associated to this object as RDF triples.

105 TRIPLES      21 PREDICATES      31 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00298768 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author Nbe737529492343ca9ab8ba17d5fdb231
4 schema:citation sg:pub.10.1007/bf00255211
5 https://doi.org/10.1002/apmc.1990.051790107
6 https://doi.org/10.1016/0032-3861(83)90148-9
7 https://doi.org/10.1080/00222338708076935
8 schema:datePublished 1993-07
9 schema:datePublishedReg 1993-07-01
10 schema:description Reaction conditions leading to the smallest amount of unreacted isocyanate groups for the preparation of poly(urethane-isocyanurate) networks based on 2,4-tolylene diisocyanate and α,ω-dihydroxypoly(oxypropylene) (Mn = 425−) were found. A tertiary amine, POLYCAT* 41, was used as a cyclotrimerization catalyst. The networks were prepared by prepolymer two-stage technique. The content of isocyanate groups in the prepolymers and networks was determined by potentiometric titration. Model reactions in 1,4-dioxane were used for the estimation of possible reaction intermediates during poly(urethane-isocyanurate) synthesis.
11 schema:genre research_article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N114fbd084f634062b9794d0b89b2cf18
15 Neefc111576914732abb46b3ebed16bea
16 sg:journal.1123778
17 schema:name Formation of poly(urethane-isocyanurate) networks from poly(oxypropylene)diols and diisocyanate
18 schema:pagination 83-88
19 schema:productId N0c3484d5717743648907119e78d08308
20 N2f4be7b73670444d8adf75a827ebf8a1
21 N7c29a579f4784d01bfdcda25ddcc6038
22 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040348481
23 https://doi.org/10.1007/bf00298768
24 schema:sdDatePublished 2019-04-15T08:54
25 schema:sdLicense https://scigraph.springernature.com/explorer/license/
26 schema:sdPublisher N60461fc357824c82a3d48e6372a5a169
27 schema:url http://link.springer.com/10.1007/BF00298768
28 sgo:license sg:explorer/license/
29 sgo:sdDataset articles
30 rdf:type schema:ScholarlyArticle
31 N0c3484d5717743648907119e78d08308 schema:name dimensions_id
32 schema:value pub.1040348481
33 rdf:type schema:PropertyValue
34 N114fbd084f634062b9794d0b89b2cf18 schema:volumeNumber 31
35 rdf:type schema:PublicationVolume
36 N234dc84c76fd49dfb6fc3e2167acec0e rdf:first sg:person.01151570140.64
37 rdf:rest rdf:nil
38 N2f4be7b73670444d8adf75a827ebf8a1 schema:name doi
39 schema:value 10.1007/bf00298768
40 rdf:type schema:PropertyValue
41 N5764298f674940189d5d94e961b6f5f6 rdf:first sg:person.016154462031.90
42 rdf:rest N234dc84c76fd49dfb6fc3e2167acec0e
43 N5df571287c3c49a5aa5a2132b11c9238 rdf:first sg:person.011376060235.02
44 rdf:rest N9a2f0bab56504085a052dcbbec4df0be
45 N60461fc357824c82a3d48e6372a5a169 schema:name Springer Nature - SN SciGraph project
46 rdf:type schema:Organization
47 N7c29a579f4784d01bfdcda25ddcc6038 schema:name readcube_id
48 schema:value c033c8d46998c671765318bb8e0ba28521f14d35257e483d314ddb919fd0316b
49 rdf:type schema:PropertyValue
50 N9a2f0bab56504085a052dcbbec4df0be rdf:first sg:person.013710523716.57
51 rdf:rest N5764298f674940189d5d94e961b6f5f6
52 Nbe737529492343ca9ab8ba17d5fdb231 rdf:first sg:person.011363663463.39
53 rdf:rest N5df571287c3c49a5aa5a2132b11c9238
54 Neefc111576914732abb46b3ebed16bea schema:issueNumber 1
55 rdf:type schema:PublicationIssue
56 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
57 schema:name Chemical Sciences
58 rdf:type schema:DefinedTerm
59 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
60 schema:name Organic Chemistry
61 rdf:type schema:DefinedTerm
62 sg:journal.1123778 schema:issn 0170-0839
63 1436-2449
64 schema:name Polymer Bulletin
65 rdf:type schema:Periodical
66 sg:person.011363663463.39 schema:affiliation https://www.grid.ac/institutes/grid.424999.b
67 schema:familyName Špírková
68 schema:givenName M.
69 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011363663463.39
70 rdf:type schema:Person
71 sg:person.011376060235.02 schema:affiliation https://www.grid.ac/institutes/grid.10822.39
72 schema:familyName Budinski-Simendic
73 schema:givenName J.
74 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011376060235.02
75 rdf:type schema:Person
76 sg:person.01151570140.64 schema:affiliation https://www.grid.ac/institutes/grid.424999.b
77 schema:familyName Dušek
78 schema:givenName K.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01151570140.64
80 rdf:type schema:Person
81 sg:person.013710523716.57 schema:affiliation https://www.grid.ac/institutes/grid.424999.b
82 schema:familyName Ilavský
83 schema:givenName M.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013710523716.57
85 rdf:type schema:Person
86 sg:person.016154462031.90 schema:affiliation https://www.grid.ac/institutes/grid.424999.b
87 schema:familyName Špaček
88 schema:givenName P.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016154462031.90
90 rdf:type schema:Person
91 sg:pub.10.1007/bf00255211 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039532314
92 https://doi.org/10.1007/bf00255211
93 rdf:type schema:CreativeWork
94 https://doi.org/10.1002/apmc.1990.051790107 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001194899
95 rdf:type schema:CreativeWork
96 https://doi.org/10.1016/0032-3861(83)90148-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002937764
97 rdf:type schema:CreativeWork
98 https://doi.org/10.1080/00222338708076935 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003965156
99 rdf:type schema:CreativeWork
100 https://www.grid.ac/institutes/grid.10822.39 schema:alternateName University of Novi Sad
101 schema:name Faculty of Technology, University of Novi Sad, Novi Sad, Yugoslavia
102 rdf:type schema:Organization
103 https://www.grid.ac/institutes/grid.424999.b schema:alternateName Institute of Macromolecular Chemistry
104 schema:name Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06, Prague 6, Czech Republic
105 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...