Molecular-mass distributions resulting from the homopolymerization of monoepoxides initiated by tertiary amines View Full Text


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Article Info

DATE

1992-06

AUTHORS

A. Vázquez, R. Deza, R. J. J. Williams

ABSTRACT

A reaction scheme based on propagation and intramolecular chain transfer steps is proposed for the anionic homopolymerization of epoxides initiated by tertiary amines. Chain transfer regenerates a living chain and gives a dead chain with terminal vinilydene unsaturations and hydroxy groups. The possibility of generating phenols or substituted phenols is also considered. Molecular-mass distributions were predicted as a function of conversion by both kinetic and Monte Carlo methods. Predictions were compared with experimental results reported in the literature. The evolution of the number-average degree of polymerization could be reasonably predicted. More... »

PAGES

459-465

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00297340

DOI

http://dx.doi.org/10.1007/bf00297340

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037629264


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