Photoreactivity of aqueous anionic NOx with hydrocarbons part I nitrite-heptane system under strong UV. radiation View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1977-01

AUTHORS

Gianna L. Petriconi, Henry M. Papee, Giorgio Cantarelli

ABSTRACT

The reduction of nitrous ions, in solutions containing heptane suspended under vigorous stirring and irradiated with a strong UV source, is investigated. The formation of ammonium is used as a monitor of the process which also leads to the concurrent production of organic nitrates and nitrites, as well as of aldehydes and nitro, nitroso and ammino derivatives. An overall mechanism of ammonium formation and destruction is proposed and tested and the effects of NOinf2sup−concentration, pH, radiation intensity and temperature are evaluated. Implications towards the importance of similar reactions which may occur under sunlight are discussed. More... »

PAGES

69-78

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00283800

DOI

http://dx.doi.org/10.1007/bf00283800

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1023779649


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