Build-up of polymer networks by initiated polyreactions View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1987-06

AUTHORS

Roberto J. J. Williams, Carmen C. Riccardi, Karel Dušek

ABSTRACT

A fragment approach, consisting of a selection of different fragments from which the network may be built-up, together with a kinetic scheme giving the evolution of such fragments during polymerization and a recursive approach for derivation of statistical averages, is used in the analysis of the build-up of polymer networks by initiated polyreactions. Gelation conditions are predicted for two simple cases: the living polymerization of a (tetrafunctional) monomer with two polymerizable groups and the polyetherification released by polyamine-polyepoxide addition. When the size of the fragments is increased, the solution converges to the exact solution given by the kinetic theory. More... »

PAGES

515-521

References to SciGraph publications

  • 1986. Network formation in curing of epoxy resins in EPOXY RESINS AND COMPOSITES III
  • 1985-04. Build-up of polymer networks by initiated polyreactions in POLYMER BULLETIN
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf00283087

    DOI

    http://dx.doi.org/10.1007/bf00283087

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1006813512


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