Ontology type: schema:ScholarlyArticle
1987-06
AUTHORSRoberto J. J. Williams, Carmen C. Riccardi, Karel Dušek
ABSTRACTA fragment approach, consisting of a selection of different fragments from which the network may be built-up, together with a kinetic scheme giving the evolution of such fragments during polymerization and a recursive approach for derivation of statistical averages, is used in the analysis of the build-up of polymer networks by initiated polyreactions. Gelation conditions are predicted for two simple cases: the living polymerization of a (tetrafunctional) monomer with two polymerizable groups and the polyetherification released by polyamine-polyepoxide addition. When the size of the fragments is increased, the solution converges to the exact solution given by the kinetic theory. More... »
PAGES515-521
http://scigraph.springernature.com/pub.10.1007/bf00283087
DOIhttp://dx.doi.org/10.1007/bf00283087
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