Solid-state high-resolution 13C-NMR studies of regenerated cellulose samples with different crystallinities View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1982-09

AUTHORS

Fumitaka Horii, Asako Hirai, Ryozo Kitamaru

ABSTRACT

CP/DD/MASS 13C-NMR spectra have been obtained for regenerated cellulose samples with different crystallinities as well as for cotton, β-D-glucose, β-D-cellobiose, and cellopentaose. The spectra of the regenerated cellulose samples exhibit broad multiplicities of the C-4 and C-6 resonance lines in a similar manner as those of native cellulose samples such as cotton and ramie, and, in addition, another broad tailing of the C-1 resonance. Since these multiplicities change linearly with crystallinity, it is concluded that they are ascribed to the contributions from the crystalline and noncrystalline components. Effects of hydrogen bonds and conformations of the β-1,4-glycosidic linkage on the chemical shifts are also discussed. More... »

PAGES

163-170

Journal

TITLE

Polymer Bulletin

ISSUE

2-4

VOLUME

8

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00263023

DOI

http://dx.doi.org/10.1007/bf00263023

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003579048


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