Photochlorination of organics by aqueous Cl− codissolved with anionic NOx− View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1978-11

AUTHORS

Claudio E. Rafanelli, Gianna L. Petriconi, Henry M. Papee

ABSTRACT

With analogy to the nitric anion, aqueous NO2− codissolved with chloride is found to promote photochlorination of some reactive organic compounds in contact with those solutions. Both overall patterns of the process and the quantum yields of this chlorine transfer into the organic phase, are found to be very similar to the patterns and yields of reactions which involved nitrates and were carried out under artificial illumination. With further analogy to those photoreactions of nitrate-chloride systems, the overall kinetics outlined in the laboratory for systems comprising nitrites are also followed, with higher quantum yields, under sunlight illumination. More... »

PAGES

413-420

References to SciGraph publications

Journal

TITLE

Water, Air, & Soil Pollution

ISSUE

4

VOLUME

10

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00250007

DOI

http://dx.doi.org/10.1007/bf00250007

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1008263781


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "National Research Council", 
          "id": "https://www.grid.ac/institutes/grid.5326.2", 
          "name": [
            "Laboratory for Aerosol Nucleation, National Research Council of Italy, Via Vettore 4 (Monte Sacro), 00141, Roma, Italy"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rafanelli", 
        "givenName": "Claudio E.", 
        "id": "sg:person.013210502271.12", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013210502271.12"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Research Council", 
          "id": "https://www.grid.ac/institutes/grid.5326.2", 
          "name": [
            "Laboratory for Aerosol Nucleation, National Research Council of Italy, Via Vettore 4 (Monte Sacro), 00141, Roma, Italy"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Petriconi", 
        "givenName": "Gianna L.", 
        "id": "sg:person.015457127657.63", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015457127657.63"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Research Council", 
          "id": "https://www.grid.ac/institutes/grid.5326.2", 
          "name": [
            "Laboratory for Aerosol Nucleation, National Research Council of Italy, Via Vettore 4 (Monte Sacro), 00141, Roma, Italy"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Papee", 
        "givenName": "Henry M.", 
        "id": "sg:person.016254510257.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016254510257.05"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf00280841", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009324435", 
          "https://doi.org/10.1007/bf00280841"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00280841", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009324435", 
          "https://doi.org/10.1007/bf00280841"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0047-2670(76)87004-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031179082"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(68)80292-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048042188"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(68)80292-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048042188"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/204142a0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049401400", 
          "https://doi.org/10.1038/204142a0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100635a005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055674672"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100784a005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055677891"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00723a001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055742725"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1978-11", 
    "datePublishedReg": "1978-11-01", 
    "description": "With analogy to the nitric anion, aqueous NO2\u2212 codissolved with chloride is found to promote photochlorination of some reactive organic compounds in contact with those solutions. Both overall patterns of the process and the quantum yields of this chlorine transfer into the organic phase, are found to be very similar to the patterns and yields of reactions which involved nitrates and were carried out under artificial illumination. With further analogy to those photoreactions of nitrate-chloride systems, the overall kinetics outlined in the laboratory for systems comprising nitrites are also followed, with higher quantum yields, under sunlight illumination.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00250007", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1320065", 
        "issn": [
          "0049-6979", 
          "1573-2932"
        ], 
        "name": "Water, Air, & Soil Pollution", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "10"
      }
    ], 
    "name": "Photochlorination of organics by aqueous Cl\u2212 codissolved with anionic NOx\u2212", 
    "pagination": "413-420", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "275e661d26c4e1f6f40b3524528c7515c44d32812d4d1384de1729bf241ab22b"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00250007"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1008263781"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00250007", 
      "https://app.dimensions.ai/details/publication/pub.1008263781"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:59", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000371_0000000371/records_130826_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF00250007"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00250007'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00250007'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00250007'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00250007'


 

This table displays all metadata directly associated to this object as RDF triples.

98 TRIPLES      21 PREDICATES      34 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00250007 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N38343474ebce4c419f8e0e1353bdccf0
4 schema:citation sg:pub.10.1007/bf00280841
5 sg:pub.10.1038/204142a0
6 https://doi.org/10.1016/0022-1902(68)80292-1
7 https://doi.org/10.1016/0047-2670(76)87004-9
8 https://doi.org/10.1021/j100635a005
9 https://doi.org/10.1021/j100784a005
10 https://doi.org/10.1021/ja00723a001
11 schema:datePublished 1978-11
12 schema:datePublishedReg 1978-11-01
13 schema:description With analogy to the nitric anion, aqueous NO2− codissolved with chloride is found to promote photochlorination of some reactive organic compounds in contact with those solutions. Both overall patterns of the process and the quantum yields of this chlorine transfer into the organic phase, are found to be very similar to the patterns and yields of reactions which involved nitrates and were carried out under artificial illumination. With further analogy to those photoreactions of nitrate-chloride systems, the overall kinetics outlined in the laboratory for systems comprising nitrites are also followed, with higher quantum yields, under sunlight illumination.
14 schema:genre research_article
15 schema:inLanguage en
16 schema:isAccessibleForFree false
17 schema:isPartOf N6365e82a9b7b476e92820606090aa18d
18 N6ffedbce433b4f3a9cc8e13ad65f1ee1
19 sg:journal.1320065
20 schema:name Photochlorination of organics by aqueous Cl− codissolved with anionic NOx−
21 schema:pagination 413-420
22 schema:productId N5ad97060488d439dbec35079cf3e15af
23 Nd1f6220630e2485083d8f002b5de960a
24 Ne39f25215d754fcd9774fec0f12952a9
25 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008263781
26 https://doi.org/10.1007/bf00250007
27 schema:sdDatePublished 2019-04-11T13:59
28 schema:sdLicense https://scigraph.springernature.com/explorer/license/
29 schema:sdPublisher Nae30e5f019184819b02ebc4abc99c7df
30 schema:url http://link.springer.com/10.1007%2FBF00250007
31 sgo:license sg:explorer/license/
32 sgo:sdDataset articles
33 rdf:type schema:ScholarlyArticle
34 N0c5005e6327e44e2b0d073f3728f76e8 rdf:first sg:person.016254510257.05
35 rdf:rest rdf:nil
36 N38343474ebce4c419f8e0e1353bdccf0 rdf:first sg:person.013210502271.12
37 rdf:rest N7f3ba22b36c749819980f0a18f3aa6ae
38 N5ad97060488d439dbec35079cf3e15af schema:name doi
39 schema:value 10.1007/bf00250007
40 rdf:type schema:PropertyValue
41 N6365e82a9b7b476e92820606090aa18d schema:issueNumber 4
42 rdf:type schema:PublicationIssue
43 N6ffedbce433b4f3a9cc8e13ad65f1ee1 schema:volumeNumber 10
44 rdf:type schema:PublicationVolume
45 N7f3ba22b36c749819980f0a18f3aa6ae rdf:first sg:person.015457127657.63
46 rdf:rest N0c5005e6327e44e2b0d073f3728f76e8
47 Nae30e5f019184819b02ebc4abc99c7df schema:name Springer Nature - SN SciGraph project
48 rdf:type schema:Organization
49 Nd1f6220630e2485083d8f002b5de960a schema:name dimensions_id
50 schema:value pub.1008263781
51 rdf:type schema:PropertyValue
52 Ne39f25215d754fcd9774fec0f12952a9 schema:name readcube_id
53 schema:value 275e661d26c4e1f6f40b3524528c7515c44d32812d4d1384de1729bf241ab22b
54 rdf:type schema:PropertyValue
55 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
56 schema:name Chemical Sciences
57 rdf:type schema:DefinedTerm
58 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
59 schema:name Organic Chemistry
60 rdf:type schema:DefinedTerm
61 sg:journal.1320065 schema:issn 0049-6979
62 1573-2932
63 schema:name Water, Air, & Soil Pollution
64 rdf:type schema:Periodical
65 sg:person.013210502271.12 schema:affiliation https://www.grid.ac/institutes/grid.5326.2
66 schema:familyName Rafanelli
67 schema:givenName Claudio E.
68 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013210502271.12
69 rdf:type schema:Person
70 sg:person.015457127657.63 schema:affiliation https://www.grid.ac/institutes/grid.5326.2
71 schema:familyName Petriconi
72 schema:givenName Gianna L.
73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015457127657.63
74 rdf:type schema:Person
75 sg:person.016254510257.05 schema:affiliation https://www.grid.ac/institutes/grid.5326.2
76 schema:familyName Papee
77 schema:givenName Henry M.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016254510257.05
79 rdf:type schema:Person
80 sg:pub.10.1007/bf00280841 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009324435
81 https://doi.org/10.1007/bf00280841
82 rdf:type schema:CreativeWork
83 sg:pub.10.1038/204142a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049401400
84 https://doi.org/10.1038/204142a0
85 rdf:type schema:CreativeWork
86 https://doi.org/10.1016/0022-1902(68)80292-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048042188
87 rdf:type schema:CreativeWork
88 https://doi.org/10.1016/0047-2670(76)87004-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031179082
89 rdf:type schema:CreativeWork
90 https://doi.org/10.1021/j100635a005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055674672
91 rdf:type schema:CreativeWork
92 https://doi.org/10.1021/j100784a005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055677891
93 rdf:type schema:CreativeWork
94 https://doi.org/10.1021/ja00723a001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055742725
95 rdf:type schema:CreativeWork
96 https://www.grid.ac/institutes/grid.5326.2 schema:alternateName National Research Council
97 schema:name Laboratory for Aerosol Nucleation, National Research Council of Italy, Via Vettore 4 (Monte Sacro), 00141, Roma, Italy
98 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...