Transition metal complexes with the thiosemicarbazide-based ligands. Part 12. Synthesis, structure and template reaction of ammine [2,4-pentane-dione S-methylisothiosemicarbazonato(2-)] nickel(II) dihydrate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-06

AUTHORS

Vukadin M. Leovac, Valerija I. Češljević, Nikolai V. Gerbeleu, Yuri A. Simonov, Aleksandar A. Dvorkin, Vladimir B. Arion

ABSTRACT

Ni(NO3)2·6H2O reacts with 2,4-pentanedione S-methylisothiosemicarbazonehydrogen iodide (H2L·HI) in aqueous solution; addition of ammonia then yields [NiL(NH3)]·2H2O, the crystal structure of which has been determined. In the square-planar [NiL(NH3)]·2H2O complex, the ligand, 2,4-pentanedione S-methylisothio-semicarbazone occupies three coordination sites with the bonds to the central atoms involving the terminal nitrogen atoms of the isothiosemicarbazide fragment [Ni−N(3) 1.831 Å and Ni−N(2) 1.842 Å] and the oxygen of the 2,4-pentanedione moiety [Ni−O 1.844 Å]. The template reaction of [NiL(NH3)]·2H2O with 2,4-pentanedione and triethyl orthoformate, HC(OEt)3, gave, by heating the complexes, NiL1(1) (L1 = dianion of the quadridentate NNNN macrocyclic ligand 2,10-bis(methylthio)-5,7,12,14-tetramethyl-1,3,4,8,9,11 -hexaazacyclotetradeca-2,4,6,9,12,-14-hexaene) and NiL2(2) (L2 = dianion of the quadridentate ONNO ligand 3-acetyl-6-thiomethyl-9-methyl-5,7,8-tri-azadodeca-3,6,9-triene-2,11-dione) presents described. More... »

PAGES

309-311

Journal

TITLE

Transition Metal Chemistry

ISSUE

3

VOLUME

18

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00207953

DOI

http://dx.doi.org/10.1007/bf00207953

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005883426


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