Organic chemical analysis on a microscopic scale using two-step laser desorption/laser ionization mass spectrometry View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1991-04

AUTHORS

L. J. Kovalenko, J. -M. Philippoz, J. R. Bucenell, R. Zenobi, R. N. Zare

ABSTRACT

The distribution of polycyclic aromatic hydrocarbons (PAHs) in the Allende meteorite has been measured using two-step laser desorption/laser multiphoton ionization mass spectrometry. This method enables in situ analysis with a spatial resolution of 1 millimeter or better of selected organic molecules. We present results showing that PAH concentrations are locally high compared to the average concentration found by analysis of pulverized samples, and are found primarily in the fine grained matrix; no PAHs were detected in the interiors of individual chondrules at our detection limit of about 0.05 parts per million. We have recently extended the spatial resolution of this instrument to 40 microns. More... »

PAGES

191-195

Journal

TITLE

Space Science Reviews

ISSUE

1-2

VOLUME

56

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00178409

DOI

http://dx.doi.org/10.1007/bf00178409

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004743265


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0301", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Analytical Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Stanford University", 
          "id": "https://www.grid.ac/institutes/grid.168010.e", 
          "name": [
            "Department of Chemistry, Stanford University, 94305, Stanford, California, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kovalenko", 
        "givenName": "L. J.", 
        "id": "sg:person.07562051255.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07562051255.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Stanford University", 
          "id": "https://www.grid.ac/institutes/grid.168010.e", 
          "name": [
            "Department of Chemistry, Stanford University, 94305, Stanford, California, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Philippoz", 
        "givenName": "J. -M.", 
        "id": "sg:person.01263401636.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01263401636.16"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Stanford University", 
          "id": "https://www.grid.ac/institutes/grid.168010.e", 
          "name": [
            "Department of Chemistry, Stanford University, 94305, Stanford, California, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bucenell", 
        "givenName": "J. R.", 
        "id": "sg:person.016125324721.22", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016125324721.22"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Stanford University", 
          "id": "https://www.grid.ac/institutes/grid.168010.e", 
          "name": [
            "Department of Chemistry, Stanford University, 94305, Stanford, California, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zenobi", 
        "givenName": "R.", 
        "id": "sg:person.01140470631.51", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01140470631.51"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Stanford University", 
          "id": "https://www.grid.ac/institutes/grid.168010.e", 
          "name": [
            "Department of Chemistry, Stanford University, 94305, Stanford, California, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zare", 
        "givenName": "R. N.", 
        "id": "sg:person.010075246350.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010075246350.09"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1021/ja00243a057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055717128"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.246.4933.1026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062538692"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1991-04", 
    "datePublishedReg": "1991-04-01", 
    "description": "The distribution of polycyclic aromatic hydrocarbons (PAHs) in the Allende meteorite has been measured using two-step laser desorption/laser multiphoton ionization mass spectrometry. This method enables in situ analysis with a spatial resolution of 1 millimeter or better of selected organic molecules. We present results showing that PAH concentrations are locally high compared to the average concentration found by analysis of pulverized samples, and are found primarily in the fine grained matrix; no PAHs were detected in the interiors of individual chondrules at our detection limit of about 0.05 parts per million. We have recently extended the spatial resolution of this instrument to 40 microns.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00178409", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1026170", 
        "issn": [
          "0038-6308", 
          "1572-9672"
        ], 
        "name": "Space Science Reviews", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1-2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "56"
      }
    ], 
    "name": "Organic chemical analysis on a microscopic scale using two-step laser desorption/laser ionization mass spectrometry", 
    "pagination": "191-195", 
    "productId": [
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00178409"
        ]
      }, 
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "1699ec38ae70fa996cd9c58776f2eca38bd6caa4cedf09d2b33e0ad3178c1f2a"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1004743265"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00178409", 
      "https://app.dimensions.ai/details/publication/pub.1004743265"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-15T08:49", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000374_0000000374/records_119727_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF00178409"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00178409'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00178409'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00178409'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00178409'


 

This table displays all metadata directly associated to this object as RDF triples.

95 TRIPLES      21 PREDICATES      29 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00178409 schema:about anzsrc-for:03
2 anzsrc-for:0301
3 schema:author Nf838efa5b63549be99c227565ee756c4
4 schema:citation https://doi.org/10.1021/ja00243a057
5 https://doi.org/10.1126/science.246.4933.1026
6 schema:datePublished 1991-04
7 schema:datePublishedReg 1991-04-01
8 schema:description The distribution of polycyclic aromatic hydrocarbons (PAHs) in the Allende meteorite has been measured using two-step laser desorption/laser multiphoton ionization mass spectrometry. This method enables in situ analysis with a spatial resolution of 1 millimeter or better of selected organic molecules. We present results showing that PAH concentrations are locally high compared to the average concentration found by analysis of pulverized samples, and are found primarily in the fine grained matrix; no PAHs were detected in the interiors of individual chondrules at our detection limit of about 0.05 parts per million. We have recently extended the spatial resolution of this instrument to 40 microns.
9 schema:genre research_article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N24543c8e94fb4dc887d13437f49c04ad
13 N8f986d56c9bc4d4597fd0ff0fa5244b4
14 sg:journal.1026170
15 schema:name Organic chemical analysis on a microscopic scale using two-step laser desorption/laser ionization mass spectrometry
16 schema:pagination 191-195
17 schema:productId N17fba9ed45c54c34baaf546824e76fbc
18 N98e94d5575e6458da91c134591e2404b
19 Ne5dc4b547b2d41cbaae9e3c82727ff8d
20 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004743265
21 https://doi.org/10.1007/bf00178409
22 schema:sdDatePublished 2019-04-15T08:49
23 schema:sdLicense https://scigraph.springernature.com/explorer/license/
24 schema:sdPublisher N0149a6930bcd44fdbdf87d2717061f6c
25 schema:url http://link.springer.com/10.1007%2FBF00178409
26 sgo:license sg:explorer/license/
27 sgo:sdDataset articles
28 rdf:type schema:ScholarlyArticle
29 N0149a6930bcd44fdbdf87d2717061f6c schema:name Springer Nature - SN SciGraph project
30 rdf:type schema:Organization
31 N17fba9ed45c54c34baaf546824e76fbc schema:name doi
32 schema:value 10.1007/bf00178409
33 rdf:type schema:PropertyValue
34 N24543c8e94fb4dc887d13437f49c04ad schema:volumeNumber 56
35 rdf:type schema:PublicationVolume
36 N369ce70a3bc2415293105c70ac2e70c6 rdf:first sg:person.016125324721.22
37 rdf:rest N9a13680c78244203910bded687515ac2
38 N4ee1b839ac714030b03982a9c831d5b5 rdf:first sg:person.010075246350.09
39 rdf:rest rdf:nil
40 N8f986d56c9bc4d4597fd0ff0fa5244b4 schema:issueNumber 1-2
41 rdf:type schema:PublicationIssue
42 N98e94d5575e6458da91c134591e2404b schema:name dimensions_id
43 schema:value pub.1004743265
44 rdf:type schema:PropertyValue
45 N9a13680c78244203910bded687515ac2 rdf:first sg:person.01140470631.51
46 rdf:rest N4ee1b839ac714030b03982a9c831d5b5
47 Nd41011e3f0cd4779a843fc0022dd7ce9 rdf:first sg:person.01263401636.16
48 rdf:rest N369ce70a3bc2415293105c70ac2e70c6
49 Ne5dc4b547b2d41cbaae9e3c82727ff8d schema:name readcube_id
50 schema:value 1699ec38ae70fa996cd9c58776f2eca38bd6caa4cedf09d2b33e0ad3178c1f2a
51 rdf:type schema:PropertyValue
52 Nf838efa5b63549be99c227565ee756c4 rdf:first sg:person.07562051255.93
53 rdf:rest Nd41011e3f0cd4779a843fc0022dd7ce9
54 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
55 schema:name Chemical Sciences
56 rdf:type schema:DefinedTerm
57 anzsrc-for:0301 schema:inDefinedTermSet anzsrc-for:
58 schema:name Analytical Chemistry
59 rdf:type schema:DefinedTerm
60 sg:journal.1026170 schema:issn 0038-6308
61 1572-9672
62 schema:name Space Science Reviews
63 rdf:type schema:Periodical
64 sg:person.010075246350.09 schema:affiliation https://www.grid.ac/institutes/grid.168010.e
65 schema:familyName Zare
66 schema:givenName R. N.
67 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010075246350.09
68 rdf:type schema:Person
69 sg:person.01140470631.51 schema:affiliation https://www.grid.ac/institutes/grid.168010.e
70 schema:familyName Zenobi
71 schema:givenName R.
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01140470631.51
73 rdf:type schema:Person
74 sg:person.01263401636.16 schema:affiliation https://www.grid.ac/institutes/grid.168010.e
75 schema:familyName Philippoz
76 schema:givenName J. -M.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01263401636.16
78 rdf:type schema:Person
79 sg:person.016125324721.22 schema:affiliation https://www.grid.ac/institutes/grid.168010.e
80 schema:familyName Bucenell
81 schema:givenName J. R.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016125324721.22
83 rdf:type schema:Person
84 sg:person.07562051255.93 schema:affiliation https://www.grid.ac/institutes/grid.168010.e
85 schema:familyName Kovalenko
86 schema:givenName L. J.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07562051255.93
88 rdf:type schema:Person
89 https://doi.org/10.1021/ja00243a057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055717128
90 rdf:type schema:CreativeWork
91 https://doi.org/10.1126/science.246.4933.1026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062538692
92 rdf:type schema:CreativeWork
93 https://www.grid.ac/institutes/grid.168010.e schema:alternateName Stanford University
94 schema:name Department of Chemistry, Stanford University, 94305, Stanford, California, USA
95 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...