Hydrodynamic investigations of the C60 fullerene effects on liquid- crystalline malonate-based dendrimers and hemidendrimers in solution View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2004-11-03

AUTHORS

P. Lavrenko , N. Yevlampieva , B. Dardel , R. Deschenaux

ABSTRACT

The [60]fullerene (C60) effects on behavior of hybrid liquid-crystalline malonate-based dendrimers and hemidendrimers, where C60 is attached directly to the start center, are investigated in dilute solutions using hydrodynamic methods. Differences were observed in diffusion–viscosity properties of hemidendrimers with and without C60. Nonmolecular dispersity of the dendrimer solutions was found. It was established that the C60 effects on the hydrodynamic properties of dendrimers is weaker than the influence of the solvent. Additionally, nonmolecularity of the solutions is primarily caused by intramolecular and intermolecular interactions of the mesogenic groups. The origins of these differences are discussed in comparison with the effects of the solvent thermodynamic quality. More... »

PAGES

61-66

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/b98014

DOI

http://dx.doi.org/10.1007/b98014

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050630245


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