Optical Spectroscopy View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1996

AUTHORS

Hans U. Güdel , Högni Weihe

ABSTRACT

In this chapter the effects of exchange coupling on the optical absorption and luminescence spectra of transition and rare earth metal compounds are illustrated by examples and discussed in simple language. After a brief Introduction, spectroscopic transitions to and from singly and doubly excited states are shown and discussed in section 2. The experimental access and the theoretical approach to energy splittings in the ground and excited states resulting from exchange interactions are treated in section 3. The main emphasis is on clusters of magnetic ions, which serve as ideal model systems to illustrate the spectroscopic effects and to introduce the molecular based concepts. The transition to systems with extended interactions including the most important theoretical aspects is made at the end of this main section. In the sections 4 and 5 the intensity enhancement and energy transfer processes resulting from exchange interactions are briefly treated. More... »

PAGES

173-197

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-94-017-2319-0_7

DOI

http://dx.doi.org/10.1007/978-94-017-2319-0_7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019514348


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0202", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Atomic, Molecular, Nuclear, Particle and Plasma Physics", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, University of Bern, Freiestrasse 3, CH-3000, Bern 9, Switzerland", 
          "id": "http://www.grid.ac/institutes/grid.5734.5", 
          "name": [
            "Department of Chemistry, University of Bern, Freiestrasse 3, CH-3000, Bern 9, Switzerland"
          ], 
          "type": "Organization"
        }, 
        "familyName": "G\u00fcdel", 
        "givenName": "Hans U.", 
        "id": "sg:person.013252041475.51", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013252041475.51"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, University of Bern, Freiestrasse 3, CH-3000, Bern 9, Switzerland", 
          "id": "http://www.grid.ac/institutes/grid.5734.5", 
          "name": [
            "Department of Chemistry, University of Bern, Freiestrasse 3, CH-3000, Bern 9, Switzerland"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Weihe", 
        "givenName": "H\u00f6gni", 
        "id": "sg:person.0721254136.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0721254136.01"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1996", 
    "datePublishedReg": "1996-01-01", 
    "description": "In this chapter the effects of exchange coupling on the optical absorption and luminescence spectra of transition and rare earth metal compounds are illustrated by examples and discussed in simple language. After a brief Introduction, spectroscopic transitions to and from singly and doubly excited states are shown and discussed in section 2. The experimental access and the theoretical approach to energy splittings in the ground and excited states resulting from exchange interactions are treated in section 3. The main emphasis is on clusters of magnetic ions, which serve as ideal model systems to illustrate the spectroscopic effects and to introduce the molecular based concepts. The transition to systems with extended interactions including the most important theoretical aspects is made at the end of this main section. In the sections 4 and 5 the intensity enhancement and energy transfer processes resulting from exchange interactions are briefly treated.", 
    "editor": [
      {
        "familyName": "Coronado", 
        "givenName": "Eugenio", 
        "type": "Person"
      }, 
      {
        "familyName": "Delha\u00e8s", 
        "givenName": "Pierre", 
        "type": "Person"
      }, 
      {
        "familyName": "Gatteschi", 
        "givenName": "Dante", 
        "type": "Person"
      }, 
      {
        "familyName": "Miller", 
        "givenName": "Joel S.", 
        "type": "Person"
      }
    ], 
    "genre": "chapter", 
    "id": "sg:pub.10.1007/978-94-017-2319-0_7", 
    "isAccessibleForFree": false, 
    "isPartOf": {
      "isbn": [
        "978-90-481-4724-3", 
        "978-94-017-2319-0"
      ], 
      "name": "Molecular Magnetism: From Molecular Assemblies to the Devices", 
      "type": "Book"
    }, 
    "keywords": [
      "excited states", 
      "exchange interaction", 
      "rare earth metal compounds", 
      "energy transfer process", 
      "optical absorption", 
      "optical spectroscopy", 
      "energy splitting", 
      "magnetic ions", 
      "spectroscopic transitions", 
      "intensity enhancement", 
      "experimental access", 
      "metal compounds", 
      "luminescence spectra", 
      "exchange coupling", 
      "spectroscopic effects", 
      "transfer process", 
      "ideal model system", 
      "transition", 
      "theoretical approach", 
      "important theoretical aspects", 
      "model system", 
      "spectroscopy", 
      "theoretical aspects", 
      "splitting", 
      "ions", 
      "extended interactions", 
      "compounds", 
      "absorption", 
      "spectra", 
      "main emphasis", 
      "coupling", 
      "state", 
      "interaction", 
      "brief introduction", 
      "enhancement", 
      "clusters", 
      "sections", 
      "main sections", 
      "ground", 
      "system", 
      "Section 4", 
      "Section 3", 
      "Section 2", 
      "effect", 
      "process", 
      "introduction", 
      "chapter", 
      "emphasis", 
      "example", 
      "approach", 
      "concept", 
      "end", 
      "aspects", 
      "access", 
      "simple language", 
      "language"
    ], 
    "name": "Optical Spectroscopy", 
    "pagination": "173-197", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1019514348"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/978-94-017-2319-0_7"
        ]
      }
    ], 
    "publisher": {
      "name": "Springer Nature", 
      "type": "Organisation"
    }, 
    "sameAs": [
      "https://doi.org/10.1007/978-94-017-2319-0_7", 
      "https://app.dimensions.ai/details/publication/pub.1019514348"
    ], 
    "sdDataset": "chapters", 
    "sdDatePublished": "2022-09-02T16:11", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220902/entities/gbq_results/chapter/chapter_16.jsonl", 
    "type": "Chapter", 
    "url": "https://doi.org/10.1007/978-94-017-2319-0_7"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/978-94-017-2319-0_7'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/978-94-017-2319-0_7'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/978-94-017-2319-0_7'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/978-94-017-2319-0_7'


 

This table displays all metadata directly associated to this object as RDF triples.

149 TRIPLES      22 PREDICATES      83 URIs      73 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/978-94-017-2319-0_7 schema:about anzsrc-for:02
2 anzsrc-for:0202
3 anzsrc-for:03
4 anzsrc-for:0302
5 anzsrc-for:0306
6 schema:author N546ba1038b574cc1a77450eec21b7a8d
7 schema:datePublished 1996
8 schema:datePublishedReg 1996-01-01
9 schema:description In this chapter the effects of exchange coupling on the optical absorption and luminescence spectra of transition and rare earth metal compounds are illustrated by examples and discussed in simple language. After a brief Introduction, spectroscopic transitions to and from singly and doubly excited states are shown and discussed in section 2. The experimental access and the theoretical approach to energy splittings in the ground and excited states resulting from exchange interactions are treated in section 3. The main emphasis is on clusters of magnetic ions, which serve as ideal model systems to illustrate the spectroscopic effects and to introduce the molecular based concepts. The transition to systems with extended interactions including the most important theoretical aspects is made at the end of this main section. In the sections 4 and 5 the intensity enhancement and energy transfer processes resulting from exchange interactions are briefly treated.
10 schema:editor N5678816ee817401ea2393cd59a036bc4
11 schema:genre chapter
12 schema:isAccessibleForFree false
13 schema:isPartOf Ne18fb0a18ccc4326a4462f9a8a944ba4
14 schema:keywords Section 2
15 Section 3
16 Section 4
17 absorption
18 access
19 approach
20 aspects
21 brief introduction
22 chapter
23 clusters
24 compounds
25 concept
26 coupling
27 effect
28 emphasis
29 end
30 energy splitting
31 energy transfer process
32 enhancement
33 example
34 exchange coupling
35 exchange interaction
36 excited states
37 experimental access
38 extended interactions
39 ground
40 ideal model system
41 important theoretical aspects
42 intensity enhancement
43 interaction
44 introduction
45 ions
46 language
47 luminescence spectra
48 magnetic ions
49 main emphasis
50 main sections
51 metal compounds
52 model system
53 optical absorption
54 optical spectroscopy
55 process
56 rare earth metal compounds
57 sections
58 simple language
59 spectra
60 spectroscopic effects
61 spectroscopic transitions
62 spectroscopy
63 splitting
64 state
65 system
66 theoretical approach
67 theoretical aspects
68 transfer process
69 transition
70 schema:name Optical Spectroscopy
71 schema:pagination 173-197
72 schema:productId N699471630e0449c9965d7063833c4d59
73 Nfcf4244119a141659c10e017fcb1eb7c
74 schema:publisher N8ae83b6f1eb849b09a4b9ac045f3d522
75 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019514348
76 https://doi.org/10.1007/978-94-017-2319-0_7
77 schema:sdDatePublished 2022-09-02T16:11
78 schema:sdLicense https://scigraph.springernature.com/explorer/license/
79 schema:sdPublisher N6e8137e16ab24812b83dfbc9f0f13248
80 schema:url https://doi.org/10.1007/978-94-017-2319-0_7
81 sgo:license sg:explorer/license/
82 sgo:sdDataset chapters
83 rdf:type schema:Chapter
84 N17ce48a68c8948cbaf85f811226081ee schema:familyName Gatteschi
85 schema:givenName Dante
86 rdf:type schema:Person
87 N1cdb4bd5e04545c890bbbf0a9d9abcab schema:familyName Miller
88 schema:givenName Joel S.
89 rdf:type schema:Person
90 N41f9d0391225435ba892aabcbbedec36 schema:familyName Coronado
91 schema:givenName Eugenio
92 rdf:type schema:Person
93 N5464a0d8b45240dc8c1904a2f43ac8f1 rdf:first N1cdb4bd5e04545c890bbbf0a9d9abcab
94 rdf:rest rdf:nil
95 N546ba1038b574cc1a77450eec21b7a8d rdf:first sg:person.013252041475.51
96 rdf:rest N5ecd81e0e0e94361ac93bfa09d22750e
97 N5678816ee817401ea2393cd59a036bc4 rdf:first N41f9d0391225435ba892aabcbbedec36
98 rdf:rest N965ad04b7355428ab1b583998896d396
99 N5ecd81e0e0e94361ac93bfa09d22750e rdf:first sg:person.0721254136.01
100 rdf:rest rdf:nil
101 N699471630e0449c9965d7063833c4d59 schema:name dimensions_id
102 schema:value pub.1019514348
103 rdf:type schema:PropertyValue
104 N6e8137e16ab24812b83dfbc9f0f13248 schema:name Springer Nature - SN SciGraph project
105 rdf:type schema:Organization
106 N8ae83b6f1eb849b09a4b9ac045f3d522 schema:name Springer Nature
107 rdf:type schema:Organisation
108 N965ad04b7355428ab1b583998896d396 rdf:first Nd300dcdbd8a1402185c028a602f2b767
109 rdf:rest Nb6d3414975c944c79c09ddcfa94d5e33
110 Nb6d3414975c944c79c09ddcfa94d5e33 rdf:first N17ce48a68c8948cbaf85f811226081ee
111 rdf:rest N5464a0d8b45240dc8c1904a2f43ac8f1
112 Nd300dcdbd8a1402185c028a602f2b767 schema:familyName Delhaès
113 schema:givenName Pierre
114 rdf:type schema:Person
115 Ne18fb0a18ccc4326a4462f9a8a944ba4 schema:isbn 978-90-481-4724-3
116 978-94-017-2319-0
117 schema:name Molecular Magnetism: From Molecular Assemblies to the Devices
118 rdf:type schema:Book
119 Nfcf4244119a141659c10e017fcb1eb7c schema:name doi
120 schema:value 10.1007/978-94-017-2319-0_7
121 rdf:type schema:PropertyValue
122 anzsrc-for:02 schema:inDefinedTermSet anzsrc-for:
123 schema:name Physical Sciences
124 rdf:type schema:DefinedTerm
125 anzsrc-for:0202 schema:inDefinedTermSet anzsrc-for:
126 schema:name Atomic, Molecular, Nuclear, Particle and Plasma Physics
127 rdf:type schema:DefinedTerm
128 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
129 schema:name Chemical Sciences
130 rdf:type schema:DefinedTerm
131 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
132 schema:name Inorganic Chemistry
133 rdf:type schema:DefinedTerm
134 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
135 schema:name Physical Chemistry (incl. Structural)
136 rdf:type schema:DefinedTerm
137 sg:person.013252041475.51 schema:affiliation grid-institutes:grid.5734.5
138 schema:familyName Güdel
139 schema:givenName Hans U.
140 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013252041475.51
141 rdf:type schema:Person
142 sg:person.0721254136.01 schema:affiliation grid-institutes:grid.5734.5
143 schema:familyName Weihe
144 schema:givenName Högni
145 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0721254136.01
146 rdf:type schema:Person
147 grid-institutes:grid.5734.5 schema:alternateName Department of Chemistry, University of Bern, Freiestrasse 3, CH-3000, Bern 9, Switzerland
148 schema:name Department of Chemistry, University of Bern, Freiestrasse 3, CH-3000, Bern 9, Switzerland
149 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...